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{:(,"Column I",,"Column II"),(("A"),[CoC...

`{:(,"Column I",,"Column II"),(("A"),[CoCl_(2)(en)_(2)]^(+),(p),"Shows geometrical isomerism only"),(("B"),[Cr("ox")_(3)]^(3-),(q),"Shows optical isomerism only"),(("C"),[RhCl_(3)(py)_(3)],(r),"Shows geometrical as well as optical isomerism"),(("D"),[ZnCl_(2)(NH_(3))_(2)],(s),"Shows no isomerism"):}`

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To solve the problem of matching the coordination complexes from Column I with their corresponding types of isomerism from Column II, we will analyze each complex step by step. ### Step 1: Analyze Complex A - [CoCl₂(en)₂]⁺ - **Structure**: This complex has a cobalt ion coordinated with two chloride ions and two ethylenediamine (en) ligands. - **Isomerism**: The arrangement of ligands can lead to cis and trans forms. Since there are two types of ligands, geometrical isomerism (cis-trans) is possible. - **Conclusion**: This complex shows geometrical isomerism only. **Hint**: Look for the presence of different ligands that can lead to cis and trans arrangements. ### Step 2: Analyze Complex B - [Cr(ox)₃]³⁻ - **Structure**: The complex consists of chromium coordinated with three oxalate (ox) ligands. - **Isomerism**: The oxalate ligand is bidentate and symmetrical, which means that it can create a chiral environment without a plane of symmetry. - **Conclusion**: This complex shows optical isomerism only. **Hint**: Check for the presence of chiral centers and absence of planes of symmetry to identify optical isomerism. ### Step 3: Analyze Complex C - [RhCl₃(py)₃] - **Structure**: This complex has rhodium coordinated with three chloride ions and three pyridine (py) ligands. - **Isomerism**: The arrangement can lead to facial (fac) and meridional (mer) isomers. The fac isomer can be optically active due to the absence of a plane of symmetry. - **Conclusion**: This complex shows both geometrical and optical isomerism. **Hint**: Identify if the complex can have facial and meridional arrangements and check for optical activity. ### Step 4: Analyze Complex D - [ZnCl₂(NH₃)₂] - **Structure**: This complex has zinc coordinated with two chloride ions and two ammonia (NH₃) ligands. - **Isomerism**: The coordination geometry is tetrahedral, which does not allow for cis-trans isomerism. Additionally, there is a plane of symmetry, meaning it cannot show optical isomerism either. - **Conclusion**: This complex shows no isomerism. **Hint**: Consider the coordination geometry and symmetry to determine if isomerism is possible. ### Final Matching: - A → p (Shows geometrical isomerism only) - B → q (Shows optical isomerism only) - C → r (Shows geometrical as well as optical isomerism) - D → s (Shows no isomerism) ### Summary of Answers: - A: p - B: q - C: r - D: s
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PRADEEP-CORDINATION COMPOUNDS-MCQ
  1. Match each coordination compound in List-I with an appropriate pair of...

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  2. {:(,"Column I",,"Column II"),(("A"),": CN :"^(-),(p),"Unidentate ligan...

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  3. {:(,"Column I",,"Column II"),(("A"),[CoCl(2)(en)(2)]^(+),(p),"Shows ge...

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  4. {:(,"Column I",,"Column II"),(("A"),[Ni(CO)(4)],(p),"Square planar"),(...

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  5. {:(,"Column I",,"Column II"),(("A"),O(2)^(-)rarrO(2)+O(2)^(2-),(p),"Re...

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  6. The number of CO bridges present in Fe(2)(CO)(9) is

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  7. The number of chelate rings present in the complex K(2) [Ni(EDTA)] is

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  8. Number of isomers formed by the coordination compound with the formula...

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  9. Number of CO groups that can be attached to chromium is

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  10. Taking CFSE value of octahedral complex (Delta(0)) as 10 Dq, the e(g) ...

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  11. The number of rings present in the structure of chlorophyll is

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  12. Total number of geometrical isomers for the complex [Rh Cl (CO) (PPh(3...

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  13. The volume (in mL) of 0.1M Ag NO(3) required for complete precipitatio...

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  14. EDTA^(4-) i9s ethylenediamine tetraacetate ion The total number of N-C...

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  15. For the octahedral complexes of Fe^(3+) is SCN^(-) ( thiocyanato-S) an...

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  16. In dilute aqueous H(2)SO(4) the complete diaquadioxalatoferrate (II) i...

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  17. In the complex acetylbromidodicarbonylbis (triethylphosphine) iron (II...

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  18. Among the complex ions, [Co(NH(2)-CH(2)-CH(2)-NH(2))(2)Cl(2)]^(+),[...

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  19. The number of geometric isomers possible for the complex [CoL(2)Cl(2)]...

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  20. The questions given below consist of Assertion (A) and Reason (R ) . U...

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