Home
Class 12
CHEMISTRY
{:(,"Column I",,"Column II"),(("A"),[Ni(...

`{:(,"Column I",,"Column II"),(("A"),[Ni(CO)_(4)],(p),"Square planar"),(("B"),[Ni(CN)_(4)]^(2-),(q),"Tetrahedral"),(("C"),[Cu(NH_(3))_(4)]^(2+),(r),"Paramagnetic"),(("D"),[FeCl_(4)]^(2-),(s),"Diamagnetic "):}`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the matching question regarding the coordination compounds in Column I with their properties in Column II, we will analyze each complex one by one. ### Step-by-Step Solution: **Step 1: Analyze Complex A - [Ni(CO)4]** - **Ligand Type**: CO is a neutral ligand. - **Oxidation State of Ni**: Since CO is neutral, the oxidation state of Ni is 0. - **Electron Configuration**: Ni in its elemental state has the configuration [Ar] 4s² 3d⁸. - **Hybridization**: The presence of four ligands (CO) suggests sp³ hybridization, leading to a tetrahedral geometry. - **Magnetism**: Since all electrons are paired, it is diamagnetic. - **Match**: A → (p) Square planar, (s) Diamagnetic. **Step 2: Analyze Complex B - [Ni(CN)4]²⁻** - **Ligand Type**: CN⁻ is a strong field ligand. - **Oxidation State of Ni**: The overall charge is -2, so Ni is in the +2 oxidation state. - **Electron Configuration**: Ni²⁺ has the configuration [Ar] 3d⁸. - **Hybridization**: The strong field ligand CN⁻ causes pairing of electrons, leading to dsp² hybridization and a square planar geometry. - **Magnetism**: Since all electrons are paired, it is diamagnetic. - **Match**: B → (q) Tetrahedral, (s) Diamagnetic. **Step 3: Analyze Complex C - [Cu(NH₃)₄]²⁺** - **Ligand Type**: NH₃ is a neutral ligand. - **Oxidation State of Cu**: The overall charge is +2, so Cu is in the +2 oxidation state. - **Electron Configuration**: Cu²⁺ has the configuration [Ar] 3d⁹. - **Hybridization**: With four ligands (NH₃), the hybridization is dsp², leading to a square planar geometry. - **Magnetism**: There is one unpaired electron, making it paramagnetic. - **Match**: C → (r) Paramagnetic. **Step 4: Analyze Complex D - [FeCl₄]²⁻** - **Ligand Type**: Cl⁻ is a weak field ligand. - **Oxidation State of Fe**: The overall charge is -2, so Fe is in the +2 oxidation state. - **Electron Configuration**: Fe²⁺ has the configuration [Ar] 3d⁶. - **Hybridization**: The weak field ligand Cl⁻ does not cause pairing, leading to sp³ hybridization and a tetrahedral geometry. - **Magnetism**: There are unpaired electrons, making it paramagnetic. - **Match**: D → (s) Diamagnetic. ### Final Matches: - A → (p) Square planar, (s) Diamagnetic - B → (q) Tetrahedral, (s) Diamagnetic - C → (r) Paramagnetic - D → (s) Diamagnetic
Promotional Banner

Topper's Solved these Questions

  • CORDINATION COMPOUNDS

    PRADEEP|Exercise Short Answer Questions|64 Videos
  • CORDINATION COMPOUNDS

    PRADEEP|Exercise Matching Type Question|5 Videos
  • CORDINATION COMPOUNDS

    PRADEEP|Exercise NCERT Exercises|32 Videos
  • CHEMISTRY IN EVERYDAY LIFE

    PRADEEP|Exercise IMPORTANT QUESTION FOR BOARD EXAMINATION|30 Videos
  • D- AND F-BLOCK ELEMENTS

    PRADEEP|Exercise IMPORTANT QUESTIONS|30 Videos

Similar Questions

Explore conceptually related problems

The correct order of matching of complex compound in column I with the properties in column II: {:(,"Column I",,"Column II",),((A),[Cr(NH_(3))_(6)]^(3+),(P),"Tetrahedral and paaramagnetic",),((B),[Co(CN)_(6)]^(3-),(Q),"Octahedral and diamagnetic",),((C ),[Ni(CN)_(4)]^(2-),(R ),"Octahedral and paramagnetic",),((D),[Ni(Cl)_(4)]^(2-),(S),"Square planar and diamagnetic",):}

{:(,"Column I",,"Column II"),((a),[Pt(NH_(3))ClBrI]^(-),(p),"Square planar"),((b),[Pt(NH_(3))ClBrNO_(2)]^(-),(q),EAN=84),((c),[Pt(NH_(3))Cl(CN)_(2)]^(-),(r),"Linkage isomers are 3"),(,,(t),"Linkage isomers are 4"):}

[Ni(CN)_(4)]^(2-) is diamagnetic while [Cr(NH_(3))_(6)]^(3+) is paramagnetic. Explain.

PRADEEP-CORDINATION COMPOUNDS-MCQ
  1. {:(,"Column I",,"Column II"),(("A"),": CN :"^(-),(p),"Unidentate ligan...

    Text Solution

    |

  2. {:(,"Column I",,"Column II"),(("A"),[CoCl(2)(en)(2)]^(+),(p),"Shows ge...

    Text Solution

    |

  3. {:(,"Column I",,"Column II"),(("A"),[Ni(CO)(4)],(p),"Square planar"),(...

    Text Solution

    |

  4. {:(,"Column I",,"Column II"),(("A"),O(2)^(-)rarrO(2)+O(2)^(2-),(p),"Re...

    Text Solution

    |

  5. The number of CO bridges present in Fe(2)(CO)(9) is

    Text Solution

    |

  6. The number of chelate rings present in the complex K(2) [Ni(EDTA)] is

    Text Solution

    |

  7. Number of isomers formed by the coordination compound with the formula...

    Text Solution

    |

  8. Number of CO groups that can be attached to chromium is

    Text Solution

    |

  9. Taking CFSE value of octahedral complex (Delta(0)) as 10 Dq, the e(g) ...

    Text Solution

    |

  10. The number of rings present in the structure of chlorophyll is

    Text Solution

    |

  11. Total number of geometrical isomers for the complex [Rh Cl (CO) (PPh(3...

    Text Solution

    |

  12. The volume (in mL) of 0.1M Ag NO(3) required for complete precipitatio...

    Text Solution

    |

  13. EDTA^(4-) i9s ethylenediamine tetraacetate ion The total number of N-C...

    Text Solution

    |

  14. For the octahedral complexes of Fe^(3+) is SCN^(-) ( thiocyanato-S) an...

    Text Solution

    |

  15. In dilute aqueous H(2)SO(4) the complete diaquadioxalatoferrate (II) i...

    Text Solution

    |

  16. In the complex acetylbromidodicarbonylbis (triethylphosphine) iron (II...

    Text Solution

    |

  17. Among the complex ions, [Co(NH(2)-CH(2)-CH(2)-NH(2))(2)Cl(2)]^(+),[...

    Text Solution

    |

  18. The number of geometric isomers possible for the complex [CoL(2)Cl(2)]...

    Text Solution

    |

  19. The questions given below consist of Assertion (A) and Reason (R ) . U...

    Text Solution

    |

  20. These questions consist of two statements each, printed as Assertion a...

    Text Solution

    |