Home
Class 12
CHEMISTRY
What will be the major organic product o...

What will be the major organic product of the following reaction?
`C_(6)H_(5)C_(2)H_(5) underset((ii)NaCN)overset((i)Br_(2),hv)to`

Text Solution

Verified by Experts

When ethylbenzene is treated with `Br_(2)` in presence of light, the bromine free radical formed during the reaction, abstracts the `alpha` (but not `beta`-) hydrogen from the ethyl group to form a resonance stabilized benzylic radical (I) which then reacts with `Br_(2)` to form 1-bromo-1-phenylethane (II). this on treatment with NaCN undergoes nucleophilic substitution to form 2-phenylpropanenitrile (III).
Promotional Banner

Topper's Solved these Questions

  • HALOALKANES AND HALOARENES

    PRADEEP|Exercise NCERT QUESTIONS AND EXERCISES WITH ANSWERS (NCERT INTEXT SOLVED QUESTIONS)|9 Videos
  • HALOALKANES AND HALOARENES

    PRADEEP|Exercise NCERT QUESTIONS AND EXERCISES WITH ANSWERS (NCERT INTEXT UNSOLVED QUESTIONS)|9 Videos
  • HALOALKANES AND HALOARENES

    PRADEEP|Exercise TEST YOUR GRIP (FILL IN THE BLANKS)|21 Videos
  • GENERAL PRINCIPLES AND PROCESSES OF ISOLATION OF ELEMENTS

    PRADEEP|Exercise Curiosity Questions|2 Videos
  • ORGANIC COMPOUNDS CONTAINING NITROGEN

    PRADEEP|Exercise IMPORTANT QUESTIONS FOR BOARD EXAMINATION|27 Videos

Similar Questions

Explore conceptually related problems

Write the major product of the following reaction C_(6)H_(5)CH_(2)CH_(3)underset(NaCN)overset(Br_(2)//Delta)to

What are the organic product formed in the following reaction ? C_(6)H_(5)-COO-CH_(3)underset((ii)H_(2)O)overset((i)LiAlH_(4))(rarr)

Predict the organic products of the following reactions : C_(6)H_(5)CHO overset(H_2NCONHNH_2)to

Predict the major product in the following reaction : C_(6)H_(5) - CH_(2)COCH_(3)underset((ii)H^(+))overset((i)CH_(3)MgBr("excess"))rarr

What is the major product in the following reaction? C_(6)H_(5)-CH=CH - CH_(3) underset(H_(2)O)overset((ii)(CH_(3)COO)_(2)Hg)rarrunderset(H_(3)O^(+))overset((ii)NaBH_(4))rarr

What are the products of the following reactions ? C_(6)H_(5)OCH_(2)CH_(2)OH underset("Heat")overset("Excess HBr")(rarr)

What is the product formed in the following reaction ? C_(6)H_(5)OH+C Cl_(4) underset((ii)H_(3)O^(+))overset((i)NaOH)to

PRADEEP-HALOALKANES AND HALOARENES-CONCEPTUAL QUESTIONS
  1. Complete the following reaction: CH(3)-CH=CH(2)underset("Peroxide")o...

    Text Solution

    |

  2. CHF(3) is less acidic than CHCl(3). Explain.

    Text Solution

    |

  3. What will be the major organic product of the following reaction? C(6...

    Text Solution

    |

  4. Write the major product (s) in the following reactions: (ii). CH(...

    Text Solution

    |

  5. Arrange the following halides in order increasing S(N^(2)) reactivity ...

    Text Solution

    |

  6. Predict the order of reactivity of the following compounds in S(N)1 re...

    Text Solution

    |

  7. Which reaction in each pair shown below will show the faster rate of d...

    Text Solution

    |

  8. The following reactions involve reactions of an alkyl bromide with two...

    Text Solution

    |

  9. The following reaction gives two products. C(6)H(5)CH(2)CHClC(6)H(5)...

    Text Solution

    |

  10. Write down the structure of the product of the following reaction. C...

    Text Solution

    |

  11. An alkyl halide (A), on reaction with magnesium in dry ether followed ...

    Text Solution

    |

  12. An alkyl halides (P) reacts with magnesium metal in presence of dry et...

    Text Solution

    |

  13. Write the major product of the following reaction: (a) CH(2)=CHBr un...

    Text Solution

    |

  14. Differentiate between chiral and achiral molecules.

    Text Solution

    |

  15. Identify and indicate the presence of centre of chirality, if any, in ...

    Text Solution

    |

  16. What is meant by chirality of a compound ? Give an example.

    Text Solution

    |

  17. What are enantiomers? Draw the structures of the possible enantiomers ...

    Text Solution

    |

  18. Distinguish between enantiomers and diastereomers.

    Text Solution

    |

  19. Differentiate between retention and inversion.

    Text Solution

    |

  20. (+-)-2-Butanol is optically inactive. Give reasons.

    Text Solution

    |