Home
Class 12
CHEMISTRY
Write the major product of the following...

Write the major product of the following reaction:
(a) `CH_(2)=CHBr underset("alcohol")overset(AgCN)to`

.

Text Solution

Verified by Experts

(a) Since vinyl halides are unreactive towards nucleophilic substitution reactions, therefore, `CH_(2)=CHBr` does not react AgCN.
`CH_(2)=CHBr underset("alcohol")overset(AgCN)to`No reaction.
(b) The initially formed less stable `1^(@)` carbocation (I) undergoes 1,2-methyl shift to give the more stable `3^(@)` carbocation (II) which then attacks the benzene ring to give. F.C. alkylation product (III),

(c) The initially formed less stable `1^(@)` carbocation (I) undergoes rearrangement by 1,2-hydride shift to form more stable `3^(@)` carbocation (II) which then attacks the toluene ring at the less hindered p-position to form p-cymene.
.
Promotional Banner

Topper's Solved these Questions

  • HALOALKANES AND HALOARENES

    PRADEEP|Exercise NCERT QUESTIONS AND EXERCISES WITH ANSWERS (NCERT INTEXT SOLVED QUESTIONS)|9 Videos
  • HALOALKANES AND HALOARENES

    PRADEEP|Exercise NCERT QUESTIONS AND EXERCISES WITH ANSWERS (NCERT INTEXT UNSOLVED QUESTIONS)|9 Videos
  • HALOALKANES AND HALOARENES

    PRADEEP|Exercise TEST YOUR GRIP (FILL IN THE BLANKS)|21 Videos
  • GENERAL PRINCIPLES AND PROCESSES OF ISOLATION OF ELEMENTS

    PRADEEP|Exercise Curiosity Questions|2 Videos
  • ORGANIC COMPOUNDS CONTAINING NITROGEN

    PRADEEP|Exercise IMPORTANT QUESTIONS FOR BOARD EXAMINATION|27 Videos

Similar Questions

Explore conceptually related problems

Write the major product of the following reaction C_(6)H_(5)CH_(2)CH_(3)underset(NaCN)overset(Br_(2)//Delta)to

The major product of the following reaction is CH_3CH_2CH= CH_2 underset(Rh "catalyst")overset(H_2//CO)(to)

The major product of the following reaction is CH_(3)C-=CH underset((ii) DI)overset((i) DCl(1 "equiv")) to

Identify the major product in the following reactions : C_(6)H_(5)-CH_(2)-underset(Br)underset( |)overset(H)overset(|)C-CH_(3) underset(Delta)overset(Alc.KOH)to ? overset(HBr)to ?

The major product of the following reaction is : C_(6)H_(5)CH_(2)-underset(Br)underset(|)overset(CH_(3))overset(|)C=CH_(2)-CH_(3)underset(C_(2)H_(5)OH)overset(C_(2)H_(5)O"N"a)to

What is the major product of the following reaction ? CH_(3)C-=C-CH_(2)-CH_(3)underset(underset("catalyst")(Cl_(2)))overset("1 mole of")rarr ?

PRADEEP-HALOALKANES AND HALOARENES-CONCEPTUAL QUESTIONS
  1. Predict the order of reactivity of the following compounds in S(N)1 re...

    Text Solution

    |

  2. Which reaction in each pair shown below will show the faster rate of d...

    Text Solution

    |

  3. The following reactions involve reactions of an alkyl bromide with two...

    Text Solution

    |

  4. The following reaction gives two products. C(6)H(5)CH(2)CHClC(6)H(5)...

    Text Solution

    |

  5. Write down the structure of the product of the following reaction. C...

    Text Solution

    |

  6. An alkyl halide (A), on reaction with magnesium in dry ether followed ...

    Text Solution

    |

  7. An alkyl halides (P) reacts with magnesium metal in presence of dry et...

    Text Solution

    |

  8. Write the major product of the following reaction: (a) CH(2)=CHBr un...

    Text Solution

    |

  9. Differentiate between chiral and achiral molecules.

    Text Solution

    |

  10. Identify and indicate the presence of centre of chirality, if any, in ...

    Text Solution

    |

  11. What is meant by chirality of a compound ? Give an example.

    Text Solution

    |

  12. What are enantiomers? Draw the structures of the possible enantiomers ...

    Text Solution

    |

  13. Distinguish between enantiomers and diastereomers.

    Text Solution

    |

  14. Differentiate between retention and inversion.

    Text Solution

    |

  15. (+-)-2-Butanol is optically inactive. Give reasons.

    Text Solution

    |

  16. Optically active 2-iodo butane on treatment with NaI in acetone gives ...

    Text Solution

    |

  17. (i) Which alkyl halide from the followng pair is chiral and undergoes ...

    Text Solution

    |

  18. Out of the various possible isomers of C7H7Cl containing a benzene rin...

    Text Solution

    |

  19. p-Chloronitrobenzene undergoes nulceophilic substitution faster than c...

    Text Solution

    |

  20. (i) Complete the following, giving the structures of the pincipal orga...

    Text Solution

    |