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Optically active 2-iodo butane on treatm...

Optically active 2-iodo butane on treatment with `NaI` in acetone gives a product which does not show optical activity. Explain briefly.

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Optically active 2-iodobutane on treatment with NaI in acetone undergoes racemization and hence the product does not show optical activity as explained below:
When optically active 21-iodobutane (I) is treated with `I^(-)` ion, it undergoes Walden inversion (`S_(N)2` raction) to give 2-iodobutane (II) which is the enantiomer of (I). Now 2-iodobutane (II) undergoes Walden inversion to give enantiomer (I). As a result of repetition of these two Walden inversion, ultimately a 50:50 mixture of the two enantiomers is obtained
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PRADEEP-HALOALKANES AND HALOARENES-CONCEPTUAL QUESTIONS
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  2. Which reaction in each pair shown below will show the faster rate of d...

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  3. The following reactions involve reactions of an alkyl bromide with two...

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  4. The following reaction gives two products. C(6)H(5)CH(2)CHClC(6)H(5)...

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  5. Write down the structure of the product of the following reaction. C...

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  6. An alkyl halide (A), on reaction with magnesium in dry ether followed ...

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  7. An alkyl halides (P) reacts with magnesium metal in presence of dry et...

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  8. Write the major product of the following reaction: (a) CH(2)=CHBr un...

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  9. Differentiate between chiral and achiral molecules.

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  10. Identify and indicate the presence of centre of chirality, if any, in ...

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  11. What is meant by chirality of a compound ? Give an example.

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  12. What are enantiomers? Draw the structures of the possible enantiomers ...

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  13. Distinguish between enantiomers and diastereomers.

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  14. Differentiate between retention and inversion.

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  15. (+-)-2-Butanol is optically inactive. Give reasons.

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  16. Optically active 2-iodo butane on treatment with NaI in acetone gives ...

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  17. (i) Which alkyl halide from the followng pair is chiral and undergoes ...

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  18. Out of the various possible isomers of C7H7Cl containing a benzene rin...

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  19. p-Chloronitrobenzene undergoes nulceophilic substitution faster than c...

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  20. (i) Complete the following, giving the structures of the pincipal orga...

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