Home
Class 12
CHEMISTRY
Name the following halides according to ...

Name the following halides according to IUPAC system and classify them asalkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halides:
(i) `(CH_(3))_(2)CHCH(Cl)CH_(3) , (ii) CH_(3)CH_(2)CH(CH_(3))CH(C_(2)H_(5))Cl`
(iii) `CH_(3)CH_(2)C(CH_(3))_(2)CH_(2)I , (iv) (CH_(3))_(3)C CH_(2)CH(Br)C_(6)H_(5)`
(v) `CH_(3)CH(CH_(3))CH(Br)CH_(3) , (vi) CH_(3)C(C_(2)H_(5))_(2)CH_(2)Br`
`(vii) CH_(3)C(Cl)(C_(2)H_(5))CH_(2)CH_(3) , (viii) CH_(3)CH=C(Cl)CH_(2)CH(CH_(3))_(2)`
(ix) `CH_(3)CH=CHC(Br)(CH_(3))_(2) (x) p-ClC_(6)H_(4)CH_(2)CH(CH_(3))_(2)`
(xi) `m-ClCH_(2)C_(6)H_(4)CH_(2)C(CH_(3))_(3) , "(xii)" o-Br-C_(6)H_(4)CH(CH_(3))CH_(2)CH_(3)`

Text Solution

Verified by Experts

(i) 2-Chloro-3-methylbutane, `2^(@)` alkyl halide, (ii) 3-Chloro-4-methylhexane , `2^(@)` alkyl halide (iii) I-Iodo-2, 2-dimethylbutane, `1^(@)` alkyl halide, (iv) 1-Bromo-3, 3-dimethyl-1-phenylbutane, `2^(@)` benzylic halide, (v) 2-Bromo-3-methylbutane, `2^(@)` alkyl halide, (vi) 1-Bromo-2-ethyl-2-methylbutane, `1^(@)` alkyl halide, (vii) 3-Chloto-3-methylpentane, `3^(@)` alkyl halide, (viii) 3-Chloro-5-methylhex-2-ene, vinylic halide (ix) 4-Bromo-4-methylpent-2-ene, allylic halide, (x) 1-Chloro-4-(2-methylpropyl)benzene, aryl halide (xi) 1-Chloromethyl-3-(2, 2-dimethylpropyl) benzene, `1^(@)` benzylic halide, (xii) 1-Bromo-2-(1-methylpropyl)benzene or 1-bromo-2-sec-butylbenzene, aryl halide.
Doubtnut Promotions Banner Mobile Dark
|

Topper's Solved these Questions

  • HALOALKANES AND HALOARENES

    PRADEEP|Exercise NCERT EXEMPLAR PROBLEMS WITH ANSWERS, HINTS AND SOLUTIONS (MULTIPLE CHOICE QUESTIONS-I)|30 Videos
  • HALOALKANES AND HALOARENES

    PRADEEP|Exercise NCERT EXEMPLAR PROBLEMS WITH ANSWERS, HINTS AND SOLUTIONS (MULTIPLE CHOICE QUESTIONS-II)|11 Videos
  • HALOALKANES AND HALOARENES

    PRADEEP|Exercise NCERT QUESTIONS AND EXERCISES WITH ANSWERS (NCERT INTEXT UNSOLVED QUESTIONS)|9 Videos
  • GENERAL PRINCIPLES AND PROCESSES OF ISOLATION OF ELEMENTS

    PRADEEP|Exercise Curiosity Questions|2 Videos
  • ORGANIC COMPOUNDS CONTAINING NITROGEN

    PRADEEP|Exercise IMPORTANT QUESTIONS FOR BOARD EXAMINATION|27 Videos

Similar Questions

Explore conceptually related problems

Name the following compounds according to IUPAC system and classify them as alkyl, allyl, benzyl (primary, secondary, tertiary) vinyl or aryl halides. (i). (CH_(3))_(2)CHCH(Cl)CH_(3) (ii). CH_(3)CH_(2)CH(CH_(3))CH(C_(2)H_(5))Cl (iii). CH_(3)CH_(2)C(CH_(3))_(2)CH_(2)I (iv). CH_(3)C(Cl)(C_(2)H_(5))CH_(2)CH_(3) (v). CH_(3)gtC(C_(2)H_(5))CH_(2)Br (vi). CH_(3)CH=C(Cl)CH_(2)CH(CH_(3))_(2) (vii). CH_(2)=CH-CH_(2)-Br (viii). CH_(3)CH=CHC(Br)(CH_(3))_(2) . (ix). m-ClCH_(2)C_(6)H_(4)CH_(2)C(CH_(3))_(3) (x). o-BrC_(6)H_(4)CH(CH_(3))CH_(2)CH_(3) (xi). (CH_(3))_(3)C CH_(2)CH(Br)C_(6)H_(5) (xii). p-ClC_(6)H_(4)CH_(2)CH(CH_(3))_(2) .

Classify the following as alkyl, vinyl, allyl or aryl halides : (i) H_(2)C=CHCHI_(2) (ii) CH_(3)CH=CFCH_(2)CH_(3) (iii) (iv) (CH_(3))_(2)C ClCH_(2)CH_(3) (v) (CH_(3))_(2)C=CHCH_(2)Br (vi) C_(6)H_(5)Br

Knowledge Check

  • The correct IUPAC name of CH_(3)CH_(2)CH(CH_(3))CH(C_(2)H_(5))_(2) is

    A
    4-Ethyl-3-methylhexane
    B
    3-Ethyl-4-methylhexane
    C
    3-Methyl-4-ethylhexane
    D
    2-Isopentylbutane.
  • Similar Questions

    Explore conceptually related problems

    Classify the following as alkyl, vinyl, allyl or aryl halides : (i) H_(2)C=CHCHI_(2) (ii) CH_(3)CH=CFCH_(2)CH_(3) (iii) (iv) (CH_(3))_(2)C ClCH_(2)CH_(3) (v) (CH_(3))_(2)C=CHCH_(2)Br (vi) C_(6)H_(5)Br

    Name the following compounds according to IUPAC system of nomenclature. (i) CH_(3)CH(CH_(3))CH_(2)CH_(2)CHO , (ii) CH_(3)CH_(2)COCH(C_(2)H_(5))CH_(2)CH_(2)Cl (iii) CH_(3)CH=CHCHO (iv) CH_(3)COCH_(2)COCH_(3) (v) CH_(3)CH(CH_(3))CH_(2)C(CH_(3))_(2)COCH_(3) (vi). (CH_(3))_(3)C CH_(2)COOH (vii) OHC C_(6)H_(4)CHO-p

    Write IUPAC names of the following compounds : (a) CH_(3)CH(Cl)CH(Br)CH_(3) (b) CHF_(2)CBrClF (c) ClCH_(2)C-=C CH_(2)Br (d) (C Cl_(3))_(3)C Cl (e) CH_(3)C(p-ClC_(6)H_(4))_(2)CH(Br)CH_(3) (f) (CH_(3))_(3)C CH=C(Cl)C_(6)H_(4)I-p (g) CH_(3)CHCl(CH_(2))_(2)C Cl_(2)C_(2)H_(5)

    Arrange the following compounds in increasing order of S_(N)1 reactivity. (i) ClCH_(2)CH = CHCH_(2)CH_(3) , CH_(3)C(Cl) = CHCH_(2)CH_(3) , CH_(3)CH = CHCH_(2)CH_(2)Cl , CH_(3)CH = CHCH(Cl)CH_(3) (ii) CH_(3)CH_(2)Br, CH_(2) = CHCH(Br)CH_(3) , CH_(2) = CHBr, CH_(3)CH(Br)CH_(3) (iii) (CH_(3))_(3)C Cl , C_(6)H_(5)C(CH_(3))_(2)Cl , (CH_(3))_(2)CHCl , CH_(3)CH_(2)CH_(2)Cl

    Predict the order of reactivity of the following compounds in dehydrohalogenation: (a) CH_(3)CH_(2)CH_(2)CH_(2)Cl, (CH_(3))_(2)CHCH_(2)Cl, (CH_(3))_(2)CH-CH_(2)Br, CH_(3)CH(Br)CH_(2)CH_(3), (CH_(3))_(3)C-Br (b) CH_(3)CH(Br)CH_(3), CH_(3)CH_(2)CH_(2)Br, (CH_(3))_(2)CHCH_(2)Br, (CH_(3))_(2)C CH_(2)Br

    How many of the following alkyl halides would react by S_(N^(1)) mechanism? CH_(3)Br,CH_(3)CH_(2)Br,CH_(3)CH_(2)CH_(2)I,(CH_(3))_(3)CBr,BrCH_(3)CH=CH_(2),C_(6)H_(5)CH_(2)Br,(CH_(3))_(3)C CH_(2)Br,C_(6)H_(5)CHBrCH_(3),CH_(3)CH=CHCH_(2)Cl . .

    Arrange the following in increasing order of their expected S_(N)1 reactivity : (i) CH_(3)CH(Br)CH_(3), CH_(3)CH_(2)Br, CH_(2)=CHBr, CH_(2)=CHCH(Br)CH_(3) (ii) ClCH_(2)CH=CHCH_(2)CH_(3), CH_(3)C(Cl)=CHCH_(2)CH_(3), CH_(3)CH=CHCH_(2)CH_(2)Cl, CH_(3)CH=CHCH(Cl)CH_(3) (iii) (CH_(3))_(3)C Cl, C_(6)H_(5)C(CH_(3))_(2)Cl,(CH_(3))_(2)CHCl, CH_(3)CH_(2)CH_(2)Cl