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S(N)1 reactions are accompanied by racem...

`S_(N)1` reactions are accompanied by racemization in optically active halides.

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Give reasons: (i). C-Cl bond length in chlorobenzene is shorter than C-Cl bond length in CH_(3)-Cl (ii). The dipole moment of chlorobenzene is less than of cyclohexyl chloride. (c). S_(N^(1)) reactions are are accompanied by racemisation is optically active alkyl halides.

A racemic mixtrue is optically inactive due to :

Which of the following set of statements regarding the S_N1 reaction shown by alkyl halide is correct here? 1. the S_N1 reaction on the chiral starting material end up with racemization of the product 2. The more stable the carbocation intermediate the faster the S_N1 reaction . 3. The added nucleophile plays no kinetic role in S_N1 reaction 4. The S_N1 reaction involves the inversion of configuration of the optically active substrate

Racemic tartaric acid is optically inactive due to

PRADEEP-HALOALKANES AND HALOARENES-ADDITIONAL QUESTIONS (SHORT ANSWER QUESTIONS)
  1. (a) The nucleophilic substitution of primary alkyl chlorides with sodi...

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  2. Out CH(3)-underset(CH(3))underset(|)(CH)-CH(2)-Cl and CH(3)-CH(2)-und...

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  3. S(N)1 reactions are accompanied by racemization in optically active ha...

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  4. Which would undergo S(N^(2)) reaction faster in the following pair and...

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  5. (a) Write the IUPAC names of all the possible structural isomers of C(...

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  6. A racemic mixtrue is optically inactive due to :

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  7. How is chlorobenzene prepared from: (i) benzene and (ii) aniline or ...

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  8. Explain the mechanism of nitration of benzene.

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  9. Complete the following reaction equations: (i) C(6)H(5)N(2)Cl+KI to ...

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  10. (a) Why does p-dichlorobenzene have a higher m.p than its o-and m-isom...

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  11. Give two reasons for low reactivity of aryl halides towards nucleophil...

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  12. Chlorobenzene is extremely less reactive towards nucleophilic substitu...

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  13. Account for the fact that halogen in chlorobenzene is less reactive th...

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  14. Give reasons: (i). C-Cl bond length in chlorobenzene is shorter than...

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  15. Account for the fact that C-X bond length in halobenzene is smaller th...

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  16. Why do alkyl halides undergo alkaline hydrolysis more easily than aryl...

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  17. Why are haloarenes more stable than haloalkanes and undergo electrophi...

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  18. Explain as to why haloarenes are much less reactive than halo-alkanes ...

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  19. Arrange the following compounds according to reactivity towards nucleo...

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  20. the presence of electron withdrawing group at ortho and para positions...

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