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Q. 2-Bromopentane is heated with potassi...

Q. 2-Bromopentane is heated with potassium in ethanol. the major product obtained is

A

2-Ethoxypentane

B

Pentane-1-

C

cis-Pentene-2

D

trans-Pentene-2

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the reaction of 2-bromopentane with potassium in ethanol, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reactants**: - The reactant is 2-bromopentane (C5H11Br), which has the structure: ``` CH3-CHBr-CH2-CH2-CH3 ``` 2. **Understand the Reaction Conditions**: - The reaction involves heating 2-bromopentane with potassium in ethanol. Potassium acts as a reducing agent, and ethanol serves as a solvent. 3. **Determine the Reaction Type**: - This reaction is a dehydrohalogenation reaction, where the bromine atom (Br) is eliminated along with a hydrogen atom from the adjacent carbon. This leads to the formation of an alkene. 4. **Identify the Elimination Mechanism**: - Since 2-bromopentane is a secondary haloalkane, the reaction will likely proceed via an E2 elimination mechanism, which is favored under strong bases or metals like potassium. 5. **Draw the Product**: - The elimination of HBr from 2-bromopentane will lead to the formation of pent-2-ene. The structure of pent-2-ene is: ``` CH3-CH=CH-CH2-CH3 ``` 6. **Consider Isomerism**: - Pent-2-ene can exist in two geometric isomers: cis and trans. The trans isomer is more stable due to less steric hindrance between the substituents. 7. **Identify the Major Product**: - The major product obtained from this reaction is **trans-2-pentene**. ### Final Answer: The major product obtained when 2-bromopentane is heated with potassium in ethanol is **trans-2-pentene**. ---

To solve the question regarding the reaction of 2-bromopentane with potassium in ethanol, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reactants**: - The reactant is 2-bromopentane (C5H11Br), which has the structure: ``` CH3-CHBr-CH2-CH2-CH3 ...
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