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Tertiary alcohols when passed over heate...

Tertiary alcohols when passed over heated copper undergo……………….to form…………………..

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Dehydration, alkenes.
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Assertion : When the vapours of a primary, secondary or tertiary alcohol are passed over heated copper at 573 K, an aldehyde or ketone is formed. Reason : Reduction of alcohols takes place

This is a tertiary alcohol :

When the vapours of tertiary butyl alcohol are passed through heated copper at 578 K, the product formed is

When vapours of isopropyl alcohol are passed over heated copper, the major product obtained is

When vapours of secondary alcohol are passed over hot copper at 573K, the product formed is :

What happens when ? (a) Sodium metal reacts with absolute alcohol. (b) Vapour of ethyl alcohol is passed through heated aluminium oxide at 633K. (c ) Glycerol is heated with KHSO_(4) . (d) Ethyl alcohol reacts with acetyl chloride. (e) Ethyl alcohol is heated with iodine and NaOH. (f) Ethyl alcohol is heated with bleaching powder. (g) Ethylene glycol is heated with concentrated H_(2)SO_(4) . (h) Isopropyl alcohol is oxidised with acidic potassium dichromate. (i) Ethyl alcohol is treated with conc. H_(2)SO_(4) under different conditions. (j) Tertiary buty alcohol is passed over heated copper at 573K.

The vapours of ethyl alcohol are passed over red hot copper at 573 K to form:

When tertiary butyl alcohol is passed over reduced copper, the reaction taking placed is

When tertiary butyl alcohol is passed over reduced copper, the reaction taking placed is

PRADEEP-ALCOHOLS, PHENOLS AND ETHERS-TEST YOUR GRIP (II. FILL IN THE BLANKS)
  1. When acetic acid reacts with ethyl alcohol In presence of conc H(2)SO(...

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  2. Reaction of phenol within the presence of aq. NaOH is called Schottenn...

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  3. The halogen acid (HI, HBr, HCl,HF) which is most reactive towards alc...

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  4. Phenol on treatment with bromine water gives………………but with bromine in ...

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  5. The reaction of phenol with a diazonium salt in weakly alkaline medium...

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  6. In the formation of salicylic acid by Reimer Tiemann reaction, phenol ...

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  7. A mixture of phenol and phthalic anhydride when heated with conc. H(2)...

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  8. Phenol forms coloured complexes with neutral..............

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  9. Benzyl alcohol and phenol can be distinguished by using

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  10. Primary, secondary and tertiary amines can be distinguished by

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  11. A primary alcohol on oxidation gives an……………..which on further oxidati...

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  12. Tertiary alcohols when passed over heated copper undergo……………….to form...

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  13. The enzyme which can catalyse the conversion of glucose to ethanol is

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  14. Absolute alcohol can be prepared from rectified spirit by

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  15. Absolute alcohol can be prepared from rectified spirit by

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  16. IUPAC name of methyl isopropyl ether is

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  17. Williamson's synthesiis involves the reaction of anwiith an.

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  18. Ethers behave as weaklysubstances due to the presence of two lone pair...

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  19. Aliphatic ehters are purified by shaking with a solution of ferrous sa...

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  20. is widely used as a solvent for the preparation of grignard reagents.

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