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Write the reactions of Williamson synthe...

Write the reactions of Williamson synthesis of 2-ethoxy-3-methylpentane starting from ethanol and 3-methylpentan-2-ol.

Text Solution

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Williamsom synthesis is a `S_(N)2` reaction, therefore, for the success of any such synthesis, the alkyl halide should be primary (unhindered or least inhindered). Thus, the alkyl halide should be derived from ethanol and the alkoxide ion from 3-methylpentan-2-ol. the complete synthesis is as follows:
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Knowledge Check

  • 2-methylpentane is :

    A
    B
    C
    D
  • In Williamson's synthesis, ethoxy ethanol iws prepared by.

    A
    passing ethanol over heated alumina
    B
    heating sodium ethaoxide with ethyl bromide
    C
    treating ethyl alcohol with excess of `H_2SO_4` at `430-440K`.
    D
    heating ehtanol with dry oxygen.
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