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Explain how does the (---OH) group attac...

Explain how does the `(---OH)` group attached to a carbon of benzene ring activate it towards electophililc substitution.

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Phenol may be regarded as a resonance hybrid of structures, As a result of +R-efffect of the OH group, the electron density in the benzene ring increases thereby facilitating the attacck by an electrophile. In other words, presence of OH group, activates the benzene ring towards electrophilic substitution reactions. further since the electron density is relatively higher at the two o- and one p- position, therefore, electrophilic substitution occurs mainly at o- and p-positions.
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PRADEEP-ALCOHOLS, PHENOLS AND ETHERS-NCERT QUESTIONS AND EXERCISES WITH ANSWERS (NCERT EXERCISES)
  1. Give two reactions that show the acidic nature of phenol. Compare the ...

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  2. Explain why is ortho-nitrophenol more acidic than ortho-methoxyphenol ...

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  3. Explain how does the (---OH) group attached to a carbon of benzene rin...

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  4. Give the equations of the following reactions: i. Oxidation of prop...

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  5. Explain the following with an example: i. Kolbe's reaction ii. R...

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  6. Write the mechanism of acid dehydration of ethanol to yield ethene.

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  7. How are the following conversions carried out ? i. Propene rarr Pro...

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  8. Name the reagents used in the following reactions: i. Oxidation of ...

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  9. Given reason for the higher boiling point of ethanol in comparison to ...

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  10. Give the IUPAC names of the following ethers: (i) C(2)H(5)OCH(2)-und...

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  11. Write the names of reagents and equations for the preparation of follo...

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  12. Illustrate with examples the limitations of Williamson's synthesis for...

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  13. How is 1-propoxyproapane synthesised from propan-1-ol ? Write mechanis...

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  14. Preparation of ethers by acid dehydration of secondary or tetiary alco...

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  15. Write the equation of the reaction of hydrogen iodide with : (i) 1-p...

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  16. Explain the fact that in aryl ethers, (i) the alkoxy group activates t...

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  17. Write the mechanism of the reaction of HI with methoxymethane.

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  18. Write the equations of the following reactions: i. Friedel-Crafts r...

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  19. Show how would you synthesize the following alcohols from appropriate ...

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  20. When 3-methylbutan-2-ol is treated with HBr, the following reaction ta...

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