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Arrange the given compouns in decreasing...

Arrange the given compouns in decreasing order of acidity and give a suitable explanation, Phenol, o-nitrophenol, o-cresol

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Due to -I and -R-effect of the `NO_(2)` group, o-nitrophenol is a stronger acid than phenol but do to +I-effect of the `CH_(3)` group, o-cresol is a weaker acid than phenol. Thus, acid strength of these three phenols increases in the order: o-cresolltphenollto-nitrophenol.
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PRADEEP-ALCOHOLS, PHENOLS AND ETHERS-NCERT EXEMPLAR PROBLEMS WITH ANSWERS, HINTS AND SOLUTION (SHORT ANSWER QUESTIONS)
  1. Out of o-nitrophenol and o-cresol which is more acidic ?

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  2. When phenol is treated with bromine water, white precipitate is obtain...

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  3. Arrange the given compouns in decreasing order of acidity and give a s...

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  4. Alcohols react with active metals e.g., Na, K etc., to give correspond...

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  5. What happens when benzene diazonium chloride is heated with water ?

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  6. Arrange the following compounds in decreasing order of acidity. H(2)...

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  7. Name the enzymes and write the reactions involved in the preparation o...

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  8. How can propan-2-one be converted into tert-butyl alcohol ?

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  9. Write the structures of the isomers of alcohols with molecular formula...

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  10. Explain why is OH group in phenols more strongly held as compared to O...

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  11. Explain why nucleophilic substitution reactions are not very common in...

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  12. Preparation of alcohols from alkenes involves the electrophilic attack...

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  13. Explain why is O=C=O non polar while R-O-R is polar ?

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  14. Why is the reactivity of all the three classes of alcohols with conc. ...

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  15. Write steps to carry out the conversion of phenol to aspirin.

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  16. Nitration is an example of aromatic electrophilic substitution and its...

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  17. In Kolbe's reactio insteaded of phenol, phenoxide ion is treated with ...

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  18. Dipole moment of phenol is smaller than that of methanol. Why ?

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  19. Ethers can be prepared by Williamson synthesis in which an alkyl halid...

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  20. Why is the C-O-H bond angle in alcohols slightly less than the tetrahe...

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