Home
Class 12
CHEMISTRY
Explain why nucleophilic substitution re...

Explain why nucleophilic substitution reactions are not very common in phenols.

Text Solution

Verified by Experts

OH group in phenols is a strong electron donating group. As a result, electron density on the benzene ring is quite high and hence it repels nucleophiles. In other words, nucleophiles cannot attack the benzene ring and hence phenols usually do not give nucleophilic substitution reactions.
Promotional Banner

Topper's Solved these Questions

  • ALCOHOLS, PHENOLS AND ETHERS

    PRADEEP|Exercise NCERT EXEMPLAR PROBLEMS WITH ANSWERS, HINTS AND SOLUTION (MATCHING TYPE QUESTIONS)|3 Videos
  • ALCOHOLS, PHENOLS AND ETHERS

    PRADEEP|Exercise NCERT EXEMPLAR PROBLEMS WITH ANSWERS, HINTS AND SOLUTION (ASSERTION AND REASON TYPE QUESTIONS)|10 Videos
  • ALCOHOLS, PHENOLS AND ETHERS

    PRADEEP|Exercise NCERT EXEMPLAR PROBLEMS WITH ANSWERS, HINTS AND SOLUTION (MULTIPLE CHOICE QUESTIONS-II)|5 Videos
  • ALDEHYDES, KETONES AND CARBOXYLIC ACIDS

    PRADEEP|Exercise IMPORTANT QUESTIONS FOR BOARD EXAMINATION|29 Videos

Similar Questions

Explore conceptually related problems

Explain why nucleophilic substitution reactions rae not very common in phenols.

Nucleophilic substitution reaction in Haloarenes

Nucleophilic Substitution Reaction|Summary

Nucleophilic Substitution Reaction|Summary

Nucleophilic Substitution Reaction|Summary

Nucleophilic Substitution Reaction|Summary

Nucleophilic Substitution Reaction|Summary

Aromatic Nucleophilic Substitution Reaction

Aromatic Nucleophilic Substitution Reaction

questions based on Nucleophilic substitution reactions

PRADEEP-ALCOHOLS, PHENOLS AND ETHERS-NCERT EXEMPLAR PROBLEMS WITH ANSWERS, HINTS AND SOLUTION (SHORT ANSWER QUESTIONS)
  1. Arrange the following compounds in decreasing order of acidity. H(2)...

    Text Solution

    |

  2. Name the enzymes and write the reactions involved in the preparation o...

    Text Solution

    |

  3. How can propan-2-one be converted into tert-butyl alcohol ?

    Text Solution

    |

  4. Write the structures of the isomers of alcohols with molecular formula...

    Text Solution

    |

  5. Explain why is OH group in phenols more strongly held as compared to O...

    Text Solution

    |

  6. Explain why nucleophilic substitution reactions are not very common in...

    Text Solution

    |

  7. Preparation of alcohols from alkenes involves the electrophilic attack...

    Text Solution

    |

  8. Explain why is O=C=O non polar while R-O-R is polar ?

    Text Solution

    |

  9. Why is the reactivity of all the three classes of alcohols with conc. ...

    Text Solution

    |

  10. Write steps to carry out the conversion of phenol to aspirin.

    Text Solution

    |

  11. Nitration is an example of aromatic electrophilic substitution and its...

    Text Solution

    |

  12. In Kolbe's reactio insteaded of phenol, phenoxide ion is treated with ...

    Text Solution

    |

  13. Dipole moment of phenol is smaller than that of methanol. Why ?

    Text Solution

    |

  14. Ethers can be prepared by Williamson synthesis in which an alkyl halid...

    Text Solution

    |

  15. Why is the C-O-H bond angle in alcohols slightly less than the tetrahe...

    Text Solution

    |

  16. Explain why low molecular mass alcohols are soluble in water ?

    Text Solution

    |

  17. Explain why p-nitrophenol is more acidic than phenol ?

    Text Solution

    |

  18. Explain why alcohols and ethers of comparable molecular mass have diff...

    Text Solution

    |

  19. The carbon-oxygen bond in phenol is slightly stronger than that in met...

    Text Solution

    |

  20. Arrange water, ethanol and phenol in increasing order of acidity and g...

    Text Solution

    |