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Why do alcohols have higher boiling poin...

Why do alcohols have higher boiling points than haloalkanes of the same molecular mass?

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Alcohols undergo extensive intermolecular H-bonding. As a result, alcohols exist as associated molecules as shown below:

Quite a large amount of energy is needed to break these H-bonds. Therefore, the boiling points of alcohols are much higher than haloalkanes of comparable molecular mass because the molecules of haloalkanes are held together only by weak dipole-dipole and van der waals forces of attraction. for example, the b.p. of methyl chloride is 249 K while that of methanol is 337.5.
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Why ethanol has higher boiling point than ethane ?

Statement 1 : Carboxylic acids have higher boiling points than alkanes of nearly same molecular weight. Statement 2 : Carboxylic acids involve hydrogen bonding.

Assertion: Alcohols have higher boiling points than ethers of comparable molecular masses. Reason: Alcohols and ethers are isomerism in nature.

The boiling points of haloalkanes follow the order:

The boiling points of haloalkanes follow the order:

PRADEEP-ALCOHOLS, PHENOLS AND ETHERS-ADDITIONAL QUESTIONS (VERY SHORT ANSWER QUESTIONS)
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  7. Why is sulphuric acid not used during the reaction of alcohols with KI...

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  8. What is the order of reactivity of HCl, HBr and HI with alcohols?

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  9. How will you convert ethanol into ethene?

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  10. Explain the relative ease of dehydration of alcohols as : tertiary gt ...

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  11. Name a reagent which converts primary alcohols exclusively to correspo...

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  12. Name the main product obtained when vapour of tert-butyl alcohol are p...

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  13. Vapours of an alcohol 'C' on passing over heated copper produce compou...

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  14. name one reagent which is used for the distinction of primary, seconda...

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  15. Arrange the following alcohols in order of increasing reactivity towar...

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  16. Which of the following alcohols give iodoform test?

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  17. How will you distinguish between 1-phenylethanol and 2-pheylethanol ?

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  18. What is rectified spirit?

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  19. Absolute alcohol is

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  20. Power alcohol is :

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