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CH(3)CH(2)-underset(CH(3))underset(|)ove...

`CH_(3)CH_(2)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)(C)-underset(OH)underset(|)(C)H-CH_(3) underset(heat)overset(H_(2)SO_(4))tounderset("Major")P`
What is the major product P in the above reactions?

A

`overset(CH_(3))overset(|)(C)H_(2)-CH_(2)-overset(CH_(3))overset(|)(C)-CH=CH_(2)`

B

`CH_(3)-overset(CH_(3))overset(|)(C)H-overset(CH_(3))overset(|)(C)H-CH=CH_(3)`

C

`CH_(3)CH_(2)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)(C)-CH=CH_(2)`

D

`CH_(3)CH_(2)-overset(H_(3)C)overset(|)(C)=overset(CH_(3))overset(|)(C)-CH_(3)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the major product P from the given reaction, we will analyze the steps involved in the dehydration of the alcohol using sulfuric acid (H₂SO₄) as a catalyst. ### Step-by-Step Solution: 1. **Identify the Starting Material**: The starting material is an alcohol with the structure: \[ CH_3CH_2C(CH_3)(OH)CH_3 \] This is a tertiary alcohol due to the presence of the hydroxyl (-OH) group attached to a carbon that is bonded to three other carbon atoms. 2. **Protonation of the Alcohol**: When the alcohol is treated with sulfuric acid (H₂SO₄), the hydroxyl group (-OH) gets protonated to form a better leaving group, water (H₂O): \[ CH_3CH_2C(CH_3)(OH)CH_3 + H^+ \rightarrow CH_3CH_2C(CH_3)(OH_2^+)CH_3 \] This results in the formation of a protonated alcohol. 3. **Formation of Carbocation**: The protonated alcohol loses water (H₂O), leading to the formation of a carbocation: \[ CH_3CH_2C^+(CH_3)CH_3 \] This carbocation is a tertiary carbocation, which is relatively stable. 4. **Carbocation Rearrangement**: The carbocation can undergo rearrangement to form a more stable carbocation. In this case, a methyl group (CH₃) can migrate from the adjacent carbon to the carbocation carbon: \[ CH_3CH_2C^+(CH_3)CH_3 \rightarrow CH_3CH_2C(CH_3)CH_2^+ \] This results in a more stable tertiary carbocation. 5. **Elimination of Beta Hydrogen**: The next step involves the elimination of a beta hydrogen (H) to form a double bond. The beta hydrogens can be removed from either of the adjacent carbons: - From the carbon adjacent to the carbocation. - From the other adjacent carbon. The elimination leads to the formation of an alkene: \[ CH_3CH_2C(CH_3)=CH_2 \] 6. **Identify the Major Product**: The major product of this dehydration reaction is: \[ CH_3CH_2C(CH_3)=CH_2 \] This compound has a double bond between the carbons, and due to the stability of the formed alkene, this is the major product. ### Final Answer: The major product P is: \[ \text{CH}_3\text{CH}_2\text{C}(\text{CH}_3)=\text{CH}_2 \]

To determine the major product P from the given reaction, we will analyze the steps involved in the dehydration of the alcohol using sulfuric acid (H₂SO₄) as a catalyst. ### Step-by-Step Solution: 1. **Identify the Starting Material**: The starting material is an alcohol with the structure: \[ CH_3CH_2C(CH_3)(OH)CH_3 ...
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PRADEEP-ALCOHOLS, PHENOLS AND ETHERS-COMPETITION FOCUS JEE (MAIN AND ADVANCED)/MEDICAL ENTRANCES SPECIAL (MULTIPLE CHOICE QUESTIONS WITH ONE CORRECT ANSWER-I)
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