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The most suitable reagent for the conver...

The most suitable reagent for the conversion of `R-CH_(2)OH to R-CHO` is

A

PCC (Pyridinium chlorochromate)

B

`KMnO_(4)`

C

`K_(2)Cr_(2)O_(7)`

D

`CrO_(3)`

Text Solution

AI Generated Solution

The correct Answer is:
To convert a primary alcohol (R-CH₂OH) to an aldehyde (R-CHO), we need to carry out an oxidation reaction. Here’s a step-by-step solution: 1. **Identify the Type of Alcohol**: - The given compound is a primary alcohol (R-CH₂OH). Primary alcohols can be oxidized to aldehydes. 2. **Understand the Oxidation Process**: - The oxidation of a primary alcohol involves the removal of two hydrogen atoms: one from the hydroxyl group (-OH) and one from the carbon atom bonded to it. This results in the formation of an aldehyde (R-CHO). 3. **Select the Appropriate Reagent**: - For the oxidation of primary alcohols to aldehydes, a mild oxidizing agent is required. Strong oxidizing agents can further oxidize aldehydes to carboxylic acids, which is not desired in this case. - The most suitable reagent for this conversion is Pyridinium Chlorochromate (PCC). PCC is a mild oxidizing agent that selectively oxidizes primary alcohols to aldehydes without over-oxidizing them to carboxylic acids. 4. **Conclusion**: - Therefore, the most suitable reagent for the conversion of R-CH₂OH to R-CHO is PCC (Pyridinium Chlorochromate). ### Final Answer: The most suitable reagent for the conversion of R-CH₂OH to R-CHO is PCC (Pyridinium Chlorochromate).

To convert a primary alcohol (R-CH₂OH) to an aldehyde (R-CHO), we need to carry out an oxidation reaction. Here’s a step-by-step solution: 1. **Identify the Type of Alcohol**: - The given compound is a primary alcohol (R-CH₂OH). Primary alcohols can be oxidized to aldehydes. 2. **Understand the Oxidation Process**: - The oxidation of a primary alcohol involves the removal of two hydrogen atoms: one from the hydroxyl group (-OH) and one from the carbon atom bonded to it. This results in the formation of an aldehyde (R-CHO). ...
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