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Accout for the following : (i) Oxidation...

Accout for the following : (i) Oxidation of toluence to `C_(6)H_(5)CHO` with `CrO_(3)` is carried out in presence of acetic anhydride.

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Write the names and strcutures of the products of following reactions : (i) Oxidation of toluene with chromium trioxide and acetic anhydride (ii) Reductive ozonolysis of 2, 3 -dimethylbut-2-ene (iii) Heating ethane with water gas in the presence of oxocatalyst (iv) Hydration of propyne with dilute H_(2)SO_(4) and HgSO_(4) .

C_(6)H_(5)CHO+NH_(3)rarr

Knowledge Check

  • C_(6)H_(5)-CH=CH-CHO is

    A
    Benzaldehyde
    B
    Salicylaldehyde
    C
    Cinamaldehyde
    D
    None of these.

  • Which of the following reagent convert C_(6)H_(5)CHO to C_(6)H_(5) COOH

    A
    Fehling solution
    B
    PCC
    C
    Tollen's reagent
    D
    `H_(2)+Ni`

  • For C_(6)H_(5)CHO which of the following is incorrect

    A
    On oxidation it yields benzoic acid
    B
    It is used in perfumery
    C
    It is an aromatic aldehyde
    D
    On reduction yields phenol