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Aldol condensation between which of the ...

Aldol condensation between which of the following two compounds followed by dehydration gives methyl vinyl ketone?

A

Formaldehyde and acetone

B

Formaldehyde and acetaldehyde

C

Two molecules of acetaldehyde

D

Two molecules of acetone

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The correct Answer is:
To determine which two compounds undergo aldol condensation followed by dehydration to yield methyl vinyl ketone, we will analyze the process step by step. ### Step-by-Step Solution: 1. **Identify Methyl Vinyl Ketone**: - Methyl vinyl ketone has the structure CH3C(=O)CH=CH2. This means it contains a ketone group (C=O) and a vinyl group (C=CH2). 2. **Consider Possible Reactants**: - The question provides options, but we will focus on the common reactants for aldol condensation: aldehydes and ketones. In this case, we will consider formaldehyde (HCHO) and acetone (CH3COCH3). 3. **Aldol Condensation Mechanism**: - **Formation of Enolate Ion**: Acetone has alpha-hydrogens that can be deprotonated to form an enolate ion. The enolate ion is formed from acetone: \[ \text{CH}_3\text{COCH}_3 \xrightarrow{\text{Base}} \text{CH}_3\text{C}^- \text{(O)}\text{CH}_3 \] - **Nucleophilic Attack**: The enolate ion then attacks the carbonyl carbon of formaldehyde: \[ \text{CH}_3\text{C}^- \text{(O)}\text{CH}_3 + \text{HCHO} \rightarrow \text{CH}_3\text{C(OH)}\text{(O)}\text{CH}_2\text{(OH)} \] 4. **Formation of β-Hydroxy Ketone**: - The product of the nucleophilic attack is a β-hydroxy ketone: \[ \text{CH}_3\text{C(OH)(O)}\text{CH}_2\text{(OH)} \] 5. **Dehydration Step**: - Upon heating, the β-hydroxy ketone undergoes dehydration (loss of water) to form methyl vinyl ketone: \[ \text{CH}_3\text{C(OH)(O)}\text{CH}_2\text{(OH)} \xrightarrow{\text{Heat}} \text{CH}_3\text{C(=O)}\text{CH=CH}_2 + \text{H}_2\text{O} \] 6. **Final Product**: - The final product after dehydration is methyl vinyl ketone (CH3C(=O)CH=CH2). ### Conclusion: The two compounds that undergo aldol condensation followed by dehydration to yield methyl vinyl ketone are **formaldehyde and acetone**.

To determine which two compounds undergo aldol condensation followed by dehydration to yield methyl vinyl ketone, we will analyze the process step by step. ### Step-by-Step Solution: 1. **Identify Methyl Vinyl Ketone**: - Methyl vinyl ketone has the structure CH3C(=O)CH=CH2. This means it contains a ketone group (C=O) and a vinyl group (C=CH2). 2. **Consider Possible Reactants**: ...
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Knowledge Check

  • Aldol condensation between which of the following compounds followed by dehydration gives methyl vinyl ketone?

    A
    Methanal and ethanal
    B
    Two moles of formaldehyde
    C
    Metsanal and propanone
    D
    Two moles of ethanal
  • Aldol condensation between which of the following compounds followed by dehydration gives mesityl oxide?

    A
    Two molecules of `CH_(3)COCH_(3)`
    B
    Two molecules of `CH_(3)CHO`
    C
    `CH_(3)CHO and HCHO`
    D
    `CH_(3)CHO and CH_(3)COCH_(3)`
  • Base catalysed condensation between the following compounds followed by dehydration gives methyl vinly ketone :

    A
    `HCHO and CH_(3)COCH_(3)`
    B
    `HCHO and CH_(3)CHO`
    C
    Two molecules of `CH_(3)CHO`
    D
    Two molecules of `CH_(3)COCH_(3)`
  • PRADEEP-ALDEHYDES, KETONES AND CARBOXYLIC ACIDS -COMPETITION FOCUS JEE (MAIN AND ADVANCED)/MEDICAL ENTRANCE SPECIEAL (MULTIPLE CHOICE QUESTIONS-I WITH ONE CORRECT ANSWER)
    1. Treatment of cyclopentanone with methyllithiumm gives which of the fo...

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    2. The cross aldol product formed when propanal acts as the electrophile ...

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    3. Aldol condensation between which of the following two compounds follow...

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    4. Identify the combination of compounds that undergo aldol condensation ...

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    5. Punderset(2.H(3)O^(+))overset(1.CH(3)MgBr)toR underset(2.Delta)overset...

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    6. Which of the following will be dehydrated most readily in alkaline med...

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    7. Acetone on heating with conc. H(2)SO(4) gives :

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    8. The diketone CH(3)-overset(overset(O)(||))(C)-(CH(2))(2)-overset(over...

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    9. Cyclohexene on ozonolysis followed by reaction with zinc dust and wate...

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    10. The major product of the following reaction is

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    11. Aldol condensation does not occur between

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    12. If the enolate ion combines with carbonyl group of ester, we get

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    13. Acetophenone when reacted with a base, C(2)H(5)ONa, yields a stable...

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    14. Self-condensation of two moles of ethyl acetate in presence of sodium ...

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    15. Predict the product in the given reaction.

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    16. In the following reaction the product E is underset(CHO)underset(|)(...

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    20. 'X'underset(("Reductive")) overset("Ozonolysis")rarr'Y'+'Z' 'Y' can ...

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