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An organic compound with the molecular f...

An organic compound with the molecular formula, `C_(8)H_(8)O` forms, 2,4-DNP derivative, reduces Tollens' reagent and udergoes Cnnizzron reaction. On vigorous oxidation it gives 1,2-benzene di-carboxylic acid. The organic compound is :

A

2-ethylbenzaldehyde

B

2-methylbenzaldehyde

C

acetophenone

D

3-methylbenzaldehyde

Text Solution

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The correct Answer is:
B

Since the organic compound with M.F. `C_(8)H_(8)O`, forms a 2,4-DNP derivative, reduces tollens' reagent and undergoes cannizzaro reaction, therefore, it must be an aldehyde without `alpha`-hydrogen/s. since on vigorous oxidation, it gives ,2-benzenedicarboxylic acid, therefore, aldehyde must be an o-substituted benzaldehyde. further, since benzaldehyde 7 carbon atoms and the given compound contains 8 carbon atoms, therefore, benzaldehyde has a `CH_(3)` group at o-position, i.e., 2-methylbenzaldehyde.
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PRADEEP-ALDEHYDES, KETONES AND CARBOXYLIC ACIDS -COMPETITION FOCUS JEE (MAIN AND ADVANCED)/MEDICAL ENTRANCE SPECIEAL (MULTIPLE CHOICE QUESTIONS-I WITH ONE CORRECT ANSWER)
  1. Identify 'Q' in the following sequence of reactions

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  2. Predict the product

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  3. An organic compound with the molecular formula, C(8)H(8)O forms, 2,4-D...

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  4. An aromatic compound X with molecular formula C(9)H(10)O gives followi...

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  5. Identify the correct method for the synthesis of the compound shown be...

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  6. Predict the product (B) in the following sequence of reactions: Ethy...

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  7. What is Z in the following sequence of reactions? Phenolunderset("du...

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  8. R-CH(2)-CH(2)OH can be converted into RCH(2)CH(2)COOH the correct seq...

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  9. The acid D obtained through the following sequence of reactions is: ...

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  10. Grignard reagents and organolithium compounds on addition to dry ice s...

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  11. Butan-2-one can be converted to propanoic acid by which of the followi...

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  12. C(6)H(5)^(11)COOH on heating with Na(2)CO(3) releases

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  13. The correct order of acidic strength of carboxylic acid is

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  14. Which of the following compounds would have the smallest value of pK(a...

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  15. Which of the following presents the correct order of the acidity in th...

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  16. The correct order of decreasing acid strength of trichloroacetic acid ...

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  17. The strongest acid amongst the following compounds is?

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  18. The decreasing order of acidity among the following compounds is : ...

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