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Arrange the following acids in order of ...

Arrange the following acids in order of their increasing acidity

A

`A lt B lt C lt D`

B

`B lt C lt A lt D`

C

`C lt B lt D lt A`

D

`C lt D lt B lt A`

Text Solution

Verified by Experts

The correct Answer is:
D

Due to ortho-effect,o-nitrobenzoic acid is the strongest acid. Further, since electron-withdrawing groups such as `NO_(2)` increase while electron-donating groups such as OH decrease the acid strength w.r.t. parent acid, therefore, the overall acedity increases in the order: `C lt D lt B lt A` i.e.,option (d) is correct.
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