Home
Class 12
CHEMISTRY
A compound undergoes the following seque...

A compound undergoes the following sequence of reactions:
`C_(3)H_(5)N overset("Hydrolysis")to underset((A))(C_(3)H_(6)O_(2)) overset(Cl_(2)//P)to underset((B))(C_(3)H_(5)O_(2)Cl) overset(NH_(3))to underset((C))(C_(3)H_(7)NO_(2))`
The compound C is

A

1-nitropropane

B

2-nitropropane

C

2-aminopropanoic acid

D

2-hydroxypropanamide.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we will analyze the sequence of reactions step by step. ### Step 1: Identify the starting compound The starting compound is given as \( C_3H_5N \). This indicates that it is likely a nitrile or an amine. Given the context of the reactions, we can assume it is a nitrile, specifically propionitrile (\( CH_3CH_2CN \)). ### Step 2: Hydrolysis of the nitrile When propionitrile undergoes hydrolysis, it reacts with water to form a carboxylic acid. The reaction can be represented as follows: \[ C_3H_5N + H_2O \rightarrow C_3H_6O_2 + NH_3 \] The product \( C_3H_6O_2 \) is propanoic acid (\( CH_3CH_2COOH \)), which corresponds to compound (A). ### Step 3: Chlorination of the carboxylic acid Next, propanoic acid undergoes chlorination in the presence of chlorine and phosphorus. This reaction typically results in the formation of an alpha-chloro acid. The reaction can be represented as: \[ C_3H_6O_2 + Cl_2 \xrightarrow{P} C_3H_5O_2Cl \] The product \( C_3H_5O_2Cl \) is alpha-chloropropanoic acid (\( CH_2ClCH_2COOH \)), which corresponds to compound (B). ### Step 4: Reaction with ammonia The final step involves the reaction of alpha-chloropropanoic acid with ammonia (\( NH_3 \)). This reaction leads to the substitution of the chlorine atom by an amino group, resulting in the formation of an amino acid. The reaction can be represented as: \[ C_3H_5O_2Cl + NH_3 \rightarrow C_3H_7NO_2 \] The product \( C_3H_7NO_2 \) is 2-aminopropanoic acid, also known as alanine, which corresponds to compound (C). ### Final Answer The compound C is 2-aminopropanoic acid (alanine), \( C_3H_7NO_2 \). ---

To solve the problem, we will analyze the sequence of reactions step by step. ### Step 1: Identify the starting compound The starting compound is given as \( C_3H_5N \). This indicates that it is likely a nitrile or an amine. Given the context of the reactions, we can assume it is a nitrile, specifically propionitrile (\( CH_3CH_2CN \)). ### Step 2: Hydrolysis of the nitrile When propionitrile undergoes hydrolysis, it reacts with water to form a carboxylic acid. The reaction can be represented as follows: ...
Promotional Banner

Topper's Solved these Questions

  • ALDEHYDES, KETONES AND CARBOXYLIC ACIDS

    PRADEEP|Exercise COMPETITION FOCUS JEE (MAIN AND ADVANCED)/MEDICAL ENTRANCE SPECIEAL (MULTIPLE CHOICE QUESTIONS-II WITH ONE OR MORE THAN ONE CORRECT ANSWER)|1 Videos
  • ALDEHYDES, KETONES AND CARBOXYLIC ACIDS

    PRADEEP|Exercise COMPETITION FOCUS JEE (MAIN AND ADVANCED)/MEDICAL ENTRANCE SPECIEAL (MULTIPLE CHOICE QUESTIONS-II WITH ONE CORRECT ANSWER)|12 Videos
  • ALDEHYDES, KETONES AND CARBOXYLIC ACIDS

    PRADEEP|Exercise VALUE BASED QUESTIONS WITH ANSWERS|3 Videos
  • ALCOHOLS, PHENOLS AND ETHERS

    PRADEEP|Exercise IMPORTANT QUESTIONS FOR BOARD EXAMINATIONS.|29 Videos
  • APPENDIX

    PRADEEP|Exercise MODEL TEST PAPER <br> (Section C )|15 Videos

Similar Questions

Explore conceptually related problems

underset((alpha))(C_(3)H_(5)N) overset("Hydrolysis")(to) underset((x)) (CH_(3)H_(6)O_(2)) underset((ii)H_(3)O^(+)) overset((i) Cl_(2)//P_("red"))to underset((y))(C_(3)H_(5)O_(2)Cl) overset (NH_(3))(to) underset((z)) (C_(3)H_(7)O_(2)) correct option (s) is/are for the above reaction.

Consider the following sequence of reactions [A](C_(3)H_(9)N) overset(NaNO_(2)//HCl) to [B] (C_(3)H_(8)O) overset(K_(2)Cr_(2)O_(7))underset(H_(2)SO_(4))to (C_(3)H_(6)O_(2))[C] The compound [A] is

In the following sequence of reactions, B is C_(6)H_(6) underset(FeCl_(3))overset(Cl_(2))to A overset(Na)to B

In the following sequence of reactions, B is C_(6)H_(6) underset(FeCl_(3))overset(Cl_(2))to A overset(Na)to B

The major product of the following reaction is : C_(6)H_(5)CH_(2)-underset(Br)underset(|)overset(CH_(3))overset(|)C=CH_(2)-CH_(3)underset(C_(2)H_(5)OH)overset(C_(2)H_(5)O"N"a)to

Identify 'M' in the following sequence of reactions underset((M))(C_(8)H_(6)Cl_(2)O)overset(NH_(3))rarrC_(8)H_(8)ClNO overset(Br_(2))underset(NaOH)rarr

PRADEEP-ALDEHYDES, KETONES AND CARBOXYLIC ACIDS -COMPETITION FOCUS JEE (MAIN AND ADVANCED)/MEDICAL ENTRANCE SPECIEAL (MULTIPLE CHOICE QUESTIONS-I WITH ONE CORRECT ANSWER)
  1. Among the following compounds, the one (s) that gives (gives) efferves...

    Text Solution

    |

  2. A liquid was mixed with ethanol and a drop of concentrated H(2) SO(4) ...

    Text Solution

    |

  3. Sodium ethoxide has reacted with ethanoyl chloride. The compound that ...

    Text Solution

    |

  4. CH(3)COOH overset(LiAlH(4))toA A+CH(3)COOH overset(H(3)O^(+))to B+H(...

    Text Solution

    |

  5. Methyl benzoate can prepared by

    Text Solution

    |

  6. CH(3)-CH(2)-overset(O)overset(||)(C )-OC(2)H(5) overset(Naoverset(**)(...

    Text Solution

    |

  7. Consider the following compounds: The correct decreasing order of...

    Text Solution

    |

  8. Which of the the following esters gets hydrolysed most easily under al...

    Text Solution

    |

  9. When CH(2)=CH -CO OH is reduced with LiAlH(4) the compound obtained wi...

    Text Solution

    |

  10. Propionic acid with Br(2)//P yields a dibromoproduct. Its structure wo...

    Text Solution

    |

  11. A compound undergoes the following sequence of reactions: C(3)H(5)N ...

    Text Solution

    |

  12. Which of the following acids on heating loses a molecul of H(2)O to fo...

    Text Solution

    |

  13. Which of the following carboxylic acids undergoes decarboxylation easi...

    Text Solution

    |

  14. The compound that undergoes decarboxylation most readily under mild co...

    Text Solution

    |

  15. The compound B is

    Text Solution

    |

  16. o-Toluic acid on reaction with Br(2) + Fe gives

    Text Solution

    |

  17. In a set of reaction, ethylbenzene yielded a product D. D should ...

    Text Solution

    |

  18. The major product in the reaction of N-phenylbenzamide with Br(2)//Fe ...

    Text Solution

    |

  19. Reaction of benzene with Me(3)C COCl in the presence of anhydrous AlCl...

    Text Solution

    |

  20. The compounds P,Q and S were separately subjected to nitration us...

    Text Solution

    |