Statement 1: Esters on reduction with `LiAlH_(4)` give alcohols while amides give primary amines.
Statement 2: Alkoxide ion is a better leaving group than amide ion.

Options

A. Statement-1 is True, statement-2 is true,statement-2 is a correct explanation for statement-1
B. Statement-1 is true, statement-2 is true, statement-2 is not a correct explanation for statement-1
C. Statement-1 is true, statement-2 is false
D. Statement-1 is false, statement-2 is true

Answer

To analyze the statements given in the question, we will break down each statement and evaluate their correctness.

### Step 1: Evaluate Statement 1
**Statement 1:** "Esters on reduction with `LiAlH_(4)` give alcohols while amides give primary amines."

- **Esters** are compounds with the functional group `RCOOR'`. When esters are reduced using lithium aluminum hydride (`LiAlH4`), they undergo reduction to yield alcohols. The reaction can be represented as:
\[ RCOOR' + LiAlH4 \rightarrow RCH2OH + R'OH \]
Here, the carbonyl group (C=O) is reduced to a primary alcohol.

- **Amides** have the general structure `RCONH2`. When amides are reduced with `LiAlH4`, they yield primary amines. The reaction can be represented as:
\[ RCONH2 + LiAlH4 \rightarrow RCH2NH2 \]
The carbonyl group is reduced to a primary amine.

Thus, Statement 1 is **True**.

### Step 2: Evaluate Statement 2
**Statement 2:** "Alkoxide ion is a better leaving group than amide ion."

- An **alkoxide ion** is the conjugate base of an alcohol and has the formula `RO-`. It is a relatively stable ion and can easily leave during nucleophilic substitution reactions.

- An **amide ion** is the conjugate base of an amide and has the formula `RCONH-`. The amide ion is a stronger base compared to the alkoxide ion and is less stable as a leaving group.

In general, weaker bases are better leaving groups. Since the alkoxide ion is a weaker base than the amide ion, it is indeed a better leaving group.

Thus, Statement 2 is **True**.

### Conclusion
Both statements are correct.

### Final Answer:
- Statement 1 is True: Esters give alcohols, and amides give primary amines upon reduction with `LiAlH4`.
- Statement 2 is True: Alkoxide ion is a better leaving group than amide ion.

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