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(a) How will you convert acetic acid int...

(a) How will you convert acetic acid into
(i) acetyl chloride, (ii) acetic anhydride, (iii) ethyl acetate and (iv) acetamide?
(b) With proper reasoning arrange them in decreasing order of their reactivity towards nucleophilic acyl substitution reactions.

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Knowledge Check

  • Arrange acetyl chloride (I), ethyl acetate (II), acetamide (III) and acetic anhydride (IV) in order of reactivity towards nucleophilic acyl substritution -

    A
    I gt IV gt II gt III
    B
    I gt II gt III gt IV
    C
    III gt II gt IV gt I
    D
    IV gt III gt II gt I

  • What will be the correct order of the reactivity of the compounds (I) MeBr (II) PhCH_2Br (III) MeCl towards nucleophilic substitution reactions?

    A
    `(I) gt (II) gt (III)`
    B
    `(III) gt (I) gt (II)`
    C
    `(II) gt (I) gt (III)`
    D
    `(I) gt (III) gt (IV)`

  • Give the decreasing order of the following in the extent of hydration or towards NA (nucleophilic addition) reaction. I. , II. III. , IV.

    A
    `(IV) gt (III) gt(II) gt (I)`
    B
    `(I) gt (II) gt (III) gt (IV)`
    C
    `(IV) gt (II) gt (III) gt (I)`
    D
    `(I) gt (III) gt (II) gt (IV)`
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