Home
Class 12
CHEMISTRY
The amine that reacts with NaNO(2)+HCl t...

The amine that reacts with `NaNO_(2)+HCl` to give yellow oily liquid is

A

ethylamine

B

diethylamine

C

isopropylamine

D

secondary butylamine

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding which amine reacts with `NaNO₂ + HCl` to give a yellow oily liquid, we can follow these steps: ### Step-by-Step Solution: 1. **Understanding the Reaction**: The reaction of amines with nitrous acid (which is generated from `NaNO₂` and `HCl`) leads to the formation of a diazonium salt. The type of amine (primary, secondary, or tertiary) will determine the outcome of this reaction. 2. **Identifying the Type of Amine**: - **Primary Amines**: React with nitrous acid to form diazonium salts, which can further decompose to give nitrogen gas and an alcohol. - **Secondary Amines**: React to form N-nitrosoamines, which are typically yellow oily liquids. - **Tertiary Amines**: Do not react with nitrous acid in the same way and do not produce diazonium salts. 3. **Conclusion on the Type of Amine**: Since the question specifies that the product is a yellow oily liquid, it indicates that the amine must be a secondary amine. This is because secondary amines react with nitrous acid to form N-nitrosoamines, which are characterized by their yellow oily appearance. 4. **Final Answer**: The amine that reacts with `NaNO₂ + HCl` to give a yellow oily liquid is a **secondary amine**.

To solve the question regarding which amine reacts with `NaNO₂ + HCl` to give a yellow oily liquid, we can follow these steps: ### Step-by-Step Solution: 1. **Understanding the Reaction**: The reaction of amines with nitrous acid (which is generated from `NaNO₂` and `HCl`) leads to the formation of a diazonium salt. The type of amine (primary, secondary, or tertiary) will determine the outcome of this reaction. 2. **Identifying the Type of Amine**: ...
Promotional Banner

Topper's Solved these Questions

  • ORGANIC COMPOUNDS CONTAINING NITROGEN

    PRADEEP|Exercise TEST YOUR GRIP FILL IN THE BLANKS|29 Videos
  • ORGANIC COMPOUNDS CONTAINING NITROGEN

    PRADEEP|Exercise CONCEPTUAL QUESTIONS|19 Videos
  • ORGANIC COMPOUNDS CONTAINING NITROGEN

    PRADEEP|Exercise IMPORTANT QUESTIONS FOR BOARD EXAMINATION|27 Videos
  • HALOALKANES AND HALOARENES

    PRADEEP|Exercise IMPORTANT QUESTIONS FOR BOARD EXAMINATION|22 Videos
  • P-BLOCK ELEMENTS

    PRADEEP|Exercise IMPORTANT QUESTIONS FOR BOARD EXAMINATION|25 Videos

Similar Questions

Explore conceptually related problems

The amine which reacts with NaNO_2 and dil. HCl to give yellow oily compound is___________.

Select and write the most appropriate answer from the given alternatives for each sub-question : The amine which reacts with nitrous acid to give yellow oily compound is :

Which on reaction with nitrous acid gives yellow oily liquid ?

PRADEEP-ORGANIC COMPOUNDS CONTAINING NITROGEN-TEST YOUR GRIP MULTIPLE CHOICE QUESTIONS
  1. Which of the following reaction will not give primary amine ?

    Text Solution

    |

  2. C(6)H(5)CONHCH(3) can be converted into C(6)H(5)CH(2)NHCH(3) by .

    Text Solution

    |

  3. CH(3)CH(2)Br underset(Delta)overset(Aq.KOH)to A underset(Delta)overset...

    Text Solution

    |

  4. Amine that cannot be prepared by Gabriel - phthalimide synthesis is:

    Text Solution

    |

  5. Choose the incoorect statement

    Text Solution

    |

  6. Which of the following is most basic?

    Text Solution

    |

  7. When primary amine reacts with choloroform in ethanolic KOH then the p...

    Text Solution

    |

  8. The amine that reacts with NaNO(2)+HCl to give yellow oily liquid is

    Text Solution

    |

  9. The major product of the following reaction, (CH(3))(2)CH-overset(NH(2...

    Text Solution

    |

  10. Ethyl amine on heating with CS(2) in presence of HgCl(2) forms

    Text Solution

    |

  11. When ethylamine is treated with CH(3)MgBr, the product is:

    Text Solution

    |

  12. What is X?

    Text Solution

    |

  13. When aniline is heated with conc. H(2)SO(4) with 455-475 K, it forms:

    Text Solution

    |

  14. Which of the following exists as a zwitterion?

    Text Solution

    |

  15. Which of the following will not undergo diazotisation?

    Text Solution

    |

  16. Which of the following compound gives dye test ?

    Text Solution

    |

  17. Which of the following will not show coupling reaction with benzenedia...

    Text Solution

    |

  18. Which of the following amine does not react with Hinsberg's reagent ?

    Text Solution

    |

  19. In the following reaction, X overset("Bromination")to Y underset(HCl...

    Text Solution

    |

  20. When benzenediazonium hydrogen sulphate is warmed with methanol, the p...

    Text Solution

    |