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Amongst the following, the strongest bas...

Amongst the following, the strongest base in aqueous medium is

A

`CH_(3)NH_(2)`

B

`NC CH_(2)NH_(2)`

C

`(CH_(3))_(2)NH`

D

`C_(6)H_(5)NHCH_(3)`

Text Solution

Verified by Experts

The correct Answer is:
C

`2^(@)` Amines are more basic than `1^(@)`, i.e., `(CH_(3))_(2)NH` is more basic than `CH_(3)NH_(2)`. Due to -1-effect of CN group, `NC CH_(2),NH_(2)` is less basic than even `CH_(3)CH_(2).C_(6)H_(5)NHCH_(3)` is less basic than both `CH_(3)NH_(2)` and `(CH_(3))_(2)NH` due to delocalization of lone pair of electrons on the N-atom into the benzene ring.
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PRADEEP-ORGANIC COMPOUNDS CONTAINING NITROGEN-NCERT EXEMPLANAR PROBLEMS WITH ANSWERS, HINTS AND SOLUTIONS (MUTIPLE CHOICE QUESTIONS-I)
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  3. Amongst the following, the strongest base in aqueous medium is

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  4. Which of the following is the weakest Bronsted base?

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  5. Benzylamne may be alkylated as shown in the following equation? C(6)...

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  6. Which of the following reagents would not be a good choice for reducin...

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  7. In order to prepare a 1^(@) amine from an alkyl halide with simultaneo...

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  8. The source of nitrogen in Gabriel syntheisis of amine is..

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  9. Amongst the given set of reactants, the most appropriate for preparing...

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  10. The best reagent for converting 2-phenylpropanamide into 2-phenylpropa...

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  11. The best reagent for converting, 2-phenylpropanamide into 1-phenyletha...

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  12. Hofmann's bromamide degradation reaction is shown by

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  13. The correct increasing order of basic strength for the following compo...

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  14. Methylamine reacts with HNO(2) to form….

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  15. The gas evolved when methylamine reacts with nitrous acid is

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  16. In the nitration of benzene using a mixture of conc. H(2)SO(4) and con...

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  17. Reduction of aromatic nitro compounds using Fe and HCl gives

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  18. The most reactive amine towards dilute hydrochloric acid is

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  19. Acid anhydrides on reaction with primary amine gives…

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  20. The reaction Aroverset(+)N(2)Cl^(-) overset(Cu//HCl)to ArCl +N(2) + ...

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