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Predict the product of reaciton for ani...

Predict the product of reaciton for aniline with bromine in non-polar solvent such as `CS_(2)`

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In non-polar solvent, the resonance structure involving separation of +ve and -ve charges are not stabilized by dipole-dipole interaction with the non-polar solvent. As a result activating effect of the `-NH_(2)` is reduced and hence monosubstitution occus only at o- and p-positions giving amixture of 2-bromoaniline (minor) and 4-bromoaniline (major).
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PRADEEP-ORGANIC COMPOUNDS CONTAINING NITROGEN-NCERT EXEMPLAR PROBLEMS WITH ANSWERS, HINTS AND SOLUTIONS (SHORT ANSWER QUESTIONS)
  1. Explain why MeNH(2) is stronger base than MeOH ?

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  2. What is the role of pyridine in the acelation reaction of amines?

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  3. Under the reaction condition (acidic, basic) the coupling reaction of ...

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  4. Predict the product of reaciton for aniline with bromine in non-polar...

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  5. Arraange the following compounds in increasing order of dipole moment?...

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  6. What is the structure and IUPAC name of the compound, allyl amine?

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  7. Write down the IUPAC name of

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  8. A compound Z with molecular formula C(3)H(9)N reacts with C(6)H(5)SO(2...

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  9. A primary amine, RNH(2) can be reacted with CH(3)-X to get secondary a...

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  10. Complete the following reaction

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  11. Why is aniline soluble in aqueous HCl?

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  12. Suggest a route by which the following conversion can be accomplished.

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  13. Identify A and B in the following reaction.

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  14. How will you carry out the follwing conversion? (i) Toluene -p-tolui...

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  15. Write following conversions (i) Nitrobenzene-Acetanilide (ii) Acet...

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  16. A solution contains 1g mol. Each of p-toluene diazonium chloride and p...

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  17. How will you bring out the following conversion?

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  18. How will you carry out the following conversions?

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  19. How you carry out the following conversion?

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  20. How will you carry out the following conversions?

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