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Which of the following shows the correct...

Which of the following shows the correct order of decreasing basicity in gas phase?

A

`(CH_(3))_(2)NH gt CH_(3)NH_(2) gt (CH_(3))_(3)N gt NH_(3)`

B

`(CH_(3))_(3)N gt (CH_(3))_(2)NH gt CH_(3)NH_(2) gt NH_(3)`

C

`(CH_(3))_(2)NH gt (CH_(3))_(3) N gt CH_(3)NH_(2) gt NH_(3)`

D

`(CH_(3))_(3)N gt CH_(3)NH_(2) gt (CH_(3))_(2)NH gt NH_(3)`

Text Solution

Verified by Experts

The correct Answer is:
B

In the gaseous phase, basicity increases as the +I-effect of the alkyl groups increases. Thus, option (b) is correct.
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  4. The correct statement regarding the basicity of arylamines is .

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  5. Considering the basic strength of amines in aqueous solution, which on...

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  6. Which of the following compounds is most basic?

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  7. The strongest base in aqueous solution among the following amines is :

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  8. Strongest base is

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  9. Among the following amines, the strongest Bronsted base is….

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  10. Basicity of CH(3)CH(2)NH(2)(I),CH(3)CONH(2)(II)and C(6)H(5)CONH(2)(III...

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  17. Order of the basic strength of the following compounds is

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  18. A compound with molecular mass 180 is acylated with CH(3)COCl to get a...

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