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The optically active compound (X) o...

The optically active compound (X)

on treatment with `NaNO_(2)//HCl` gives

A

`1^(@)` alcohol with retention of configuration

B

`2^(@)` alcohol with inversion of configuration

C

racemic mixture of `2^(@)` alcohols

D

racemic mixture of `1^(@)` alcohols

Text Solution

Verified by Experts

The correct Answer is:
C


Since carbocations are planar species, therefore nucleophilic attach by `H_(2)O` gives a racemic mixture of `2^(@)` alcohols.
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PRADEEP-ORGANIC COMPOUNDS CONTAINING NITROGEN-COMPETITION FOCUS JEE (MAIN AND ADVANCED)/MEDICAL ENTRANCE SPECIAL (MULTIPLE CHOICE QUESTIONS-I)
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  2. An organic compound 'A' on reduction give compound 'B' which on reacti...

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  5. Treatment of cyclobutylmethyamine with nitrous acid does not give .

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  6. The compound which gives an oily nitrosoamine on reaction with nitrous...

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  7. Predict the product:

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  8. Which gives black precipitate on reaction with CS(2) followed by addit...

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  9. The product of the following reaction

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  10. Which among the following amines can be directly oxidized to the corre...

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  11. Amino group, -NH(2) is ortho, para-directing group in case of aromatic...

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  12. The product(s) of the following reaction requence is(are)

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  13. In the following reaction, the structure of the major product 'X'...

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  14. Y is.

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  15. Anilinum hydrogensulphate on heating with sulphuric acid at 453-473K p...

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  16. The correct sequence of reactions to be performed to convert benzene i...

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  17. Which of the following exists as a zwitterion?

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  18. The compound that will react most readily with NaOH to from methanol i...

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  19. ltrgt The alkene formed as a major product in the above elimination re...

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  20. In the following reaction, product X is

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