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The final product in the following seque...

The final product in the following sequence of ractions is `C_(6)H_(5)NH_(2) underset(273-278K)overset(NaNO_(2)//HCl)toA overset(C_(6)H_(6)//NaOH)toB`

A

`C_(6)H_(5)N_(2)Cl`

B

`C_(6)H_(5)OH`

C

`C_(6)H_(5)-C_(6)H_(5)`

D

`C_(6)H_(5)N=NOH`

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The correct Answer is:
To solve the question regarding the sequence of reactions starting from aniline to the final product, we will break down the steps involved in the reactions: ### Step 1: Identify the starting compound The starting compound is **aniline (C₆H₅NH₂)**. ### Step 2: Reaction with NaNO₂ and HCl When aniline reacts with sodium nitrite (NaNO₂) in the presence of hydrochloric acid (HCl), it undergoes diazotization to form **Benzene Diazonium Chloride (C₆H₅N₂Cl)**. The reaction can be represented as follows: \[ \text{C}_6\text{H}_5\text{NH}_2 + \text{NaNO}_2 + \text{HCl} \rightarrow \text{C}_6\text{H}_5\text{N}_2^+\text{Cl}^- + \text{NaCl} + \text{H}_2\text{O} \] ### Step 3: Reaction with Benzene and NaOH The next step involves the reaction of the benzene diazonium chloride with benzene (C₆H₆) in the presence of sodium hydroxide (NaOH). This reaction leads to the formation of **biphenyl (C₁₂H₁₄)** and nitrogen gas (N₂) is released. The reaction can be represented as: \[ \text{C}_6\text{H}_5\text{N}_2^+\text{Cl}^- + \text{C}_6\text{H}_6 \xrightarrow{\text{NaOH}} \text{C}_6\text{H}_5\text{C}_6\text{H}_5 + \text{N}_2 + \text{HCl} \] ### Final Product Thus, the final product B is **biphenyl (C₁₂H₁₄)**. ### Summary of Steps: 1. Start with aniline (C₆H₅NH₂). 2. React with NaNO₂ and HCl to form benzene diazonium chloride (C₆H₅N₂Cl). 3. React benzene diazonium chloride with benzene and NaOH to form biphenyl (C₁₂H₁₄).

To solve the question regarding the sequence of reactions starting from aniline to the final product, we will break down the steps involved in the reactions: ### Step 1: Identify the starting compound The starting compound is **aniline (C₆H₅NH₂)**. ### Step 2: Reaction with NaNO₂ and HCl When aniline reacts with sodium nitrite (NaNO₂) in the presence of hydrochloric acid (HCl), it undergoes diazotization to form **Benzene Diazonium Chloride (C₆H₅N₂Cl)**. The reaction can be represented as follows: ...
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PRADEEP-ORGANIC COMPOUNDS CONTAINING NITROGEN-COMPETITION FOCUS JEE (MAIN AND ADVANCED)/MEDICAL ENTRANCE SPECIAL (MULTIPLE CHOICE QUESTIONS-I)
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  2. Which of the following statements about primary amines is false ? .

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  3. During preparation of arenediazonium salts the excess of nitrous acid,...

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  4. In the diazotisation of anline with sodium nitrite and hydrochloride a...

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  5. Which of the following diazonium salt is most stable ?

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  6. In the diazotisation of aryl amine, the use of nitrous acid is:

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  7. Which of the following will be most stable diazonium salt RN2^(+)X^(-)...

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  9. 4-Nitrotoluene is treated with bromine to get a cornpound 'P'. 'P' i...

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  10. In the following reaction , B is Aoverset("Bromination")toBoverset(Na...

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  11. The correct sequence of reactions to convert p-nitrophenol into quinol...

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  12. Aniline is reacted with bromine water and the resulting product is tre...

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  13. In the chemical reactions. the compounds 'A' and 'B' respectively...

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  14. The final product in the following reaction sequence is p - chloroan...

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  15. Which of the following is the best method for synthesis of 1 - bromo -...

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  16. In the reaction, The product (E) is

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  17. The final product in the following sequence of ractions is C(6)H(5)NH(...

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  18. Complete reduction of benzene-diazonium chloride with Zn/HCl gives :

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