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In the neutralization of Na(2)S(2)O(3) u...

In the neutralization of `Na_(2)S_(2)O_(3)` using `K_(2)Cr_(2)O_(7)` by idometry, the equivalent weight of `K_(2)Cr_(2)O_(7)` is

A

`("molecular weight")//2`

B

`("molecular weight")//6`

C

`("molecular weight")//3`

D

same as molecular weight

Text Solution

Verified by Experts

The correct Answer is:
b

`Cr_(2)O_(7)^(2-)+14H^(+)+6e^(-)rarr2Cr+7H_(2)O` since `K_(2)Cr_(2)O_(7)` accepts 6 electrons for its redcution to `Cr^(3+)` ions
`therefore` Eq wt=Mol wt/ 6
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