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A hydrogen like atom (atomic number Z) i...

A hydrogen like atom (atomic number Z) is in a higher excited state of quantum number 'n' this excited atom can make a transition to the first excited state by emitting a photon of first `27.2eV`. Alternatively the atom from the same excited state can make a transition of energy `10.20eV` the value of `n` and `z` are given (ionization energy of hydrogen atom is 13.6eV)

A

`n==6` and `z=3`

B

`n=3` and `z=6`

C

`n=8` and `z=4`

D

`n=4` and `z=8`

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The correct Answer is:
To solve the problem, we will use the energy level formula for hydrogen-like atoms and the given transition energies to find the values of \( n \) and \( Z \). ### Step-by-Step Solution: 1. **Understanding the Energy Levels**: The energy of the nth level of a hydrogen-like atom is given by: \[ E_n = -\frac{13.6 Z^2}{n^2} \text{ eV} \] where \( Z \) is the atomic number. 2. **Transition Energy**: The energy difference between two levels \( n_1 \) and \( n_2 \) is given by: \[ \Delta E = E_{n_1} - E_{n_2} = 13.6 Z^2 \left( \frac{1}{n_1^2} - \frac{1}{n_2^2} \right) \] 3. **First Transition**: The atom is in a higher excited state \( n \) and transitions to the first excited state \( n_1 = 2 \) with an energy emission of \( 27.2 \text{ eV} \): \[ 27.2 = 13.6 Z^2 \left( \frac{1}{2^2} - \frac{1}{n^2} \right) \] Simplifying this: \[ 27.2 = 13.6 Z^2 \left( \frac{1}{4} - \frac{1}{n^2} \right) \] Dividing both sides by \( 13.6 \): \[ 2 = Z^2 \left( \frac{1}{4} - \frac{1}{n^2} \right) \] Rearranging gives: \[ \frac{1}{4} - \frac{1}{n^2} = \frac{2}{Z^2} \] 4. **Second Transition**: The atom transitions to the second excited state \( n_1 = 3 \) with an energy emission of \( 10.20 \text{ eV} \): \[ 10.20 = 13.6 Z^2 \left( \frac{1}{3^2} - \frac{1}{n^2} \right) \] Simplifying this: \[ 10.20 = 13.6 Z^2 \left( \frac{1}{9} - \frac{1}{n^2} \right) \] Dividing both sides by \( 13.6 \): \[ 0.75 = Z^2 \left( \frac{1}{9} - \frac{1}{n^2} \right) \] Rearranging gives: \[ \frac{1}{9} - \frac{1}{n^2} = \frac{0.75}{Z^2} \] 5. **Setting Up the Equations**: We now have two equations: - From the first transition: \[ \frac{1}{4} - \frac{1}{n^2} = \frac{2}{Z^2} \quad \text{(1)} \] - From the second transition: \[ \frac{1}{9} - \frac{1}{n^2} = \frac{0.75}{Z^2} \quad \text{(2)} \] 6. **Eliminating \( \frac{1}{n^2} \)**: Subtract equation (1) from equation (2): \[ \left( \frac{1}{9} - \frac{1}{4} \right) = \left( \frac{0.75}{Z^2} - \frac{2}{Z^2} \right) \] Simplifying the left side: \[ \frac{1}{9} - \frac{1}{4} = \frac{4 - 9}{36} = -\frac{5}{36} \] Simplifying the right side: \[ \frac{0.75 - 2}{Z^2} = -\frac{1.25}{Z^2} \] Setting them equal gives: \[ -\frac{5}{36} = -\frac{1.25}{Z^2} \] Cross-multiplying: \[ 5Z^2 = 1.25 \times 36 \] \[ 5Z^2 = 45 \Rightarrow Z^2 = 9 \Rightarrow Z = 3 \] 7. **Finding \( n \)**: Substitute \( Z = 3 \) back into either equation to find \( n \). Using equation (1): \[ \frac{1}{4} - \frac{1}{n^2} = \frac{2}{3^2} = \frac{2}{9} \] Rearranging gives: \[ \frac{1}{n^2} = \frac{1}{4} - \frac{2}{9} \] Finding a common denominator (36): \[ \frac{1}{n^2} = \frac{9}{36} - \frac{8}{36} = \frac{1}{36} \] Thus: \[ n^2 = 36 \Rightarrow n = 6 \] ### Final Answer: The values are \( n = 6 \) and \( Z = 3 \).

To solve the problem, we will use the energy level formula for hydrogen-like atoms and the given transition energies to find the values of \( n \) and \( Z \). ### Step-by-Step Solution: 1. **Understanding the Energy Levels**: The energy of the nth level of a hydrogen-like atom is given by: \[ E_n = -\frac{13.6 Z^2}{n^2} \text{ eV} ...
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