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In a certain electronic transition in t...

In a certain electronic transition in the hydrogen atoms from an initial state `(1)` to a final state `(2)`, the difference in the orbit radius `((r_(1)-r_(2))` is 24 times the first Bohr radius. Identify the transition-

A

`5rarr1`

B

`25rarr1`

C

`8rarr3`

D

`7rarr5`

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To solve the problem of identifying the electronic transition in a hydrogen atom based on the given difference in orbit radius, we can follow these steps: ### Step-by-Step Solution: 1. **Understand the Problem**: We need to identify the transition from an initial state (n1) to a final state (n2) in a hydrogen atom, given that the difference in orbit radius (r1 - r2) is 24 times the first Bohr radius (r0). 2. **Recall the Formula for Bohr Radius**: The radius of the nth orbit in a hydrogen atom is given by the formula: \[ r_n = n^2 \cdot r_0 \] where \( r_0 \) is the first Bohr radius. 3. **Express the Difference in Radii**: The difference in the radii can be expressed as: \[ r_1 - r_2 = r_{n1} - r_{n2} = (n1^2 \cdot r_0) - (n2^2 \cdot r_0) = r_0(n1^2 - n2^2) \] 4. **Set Up the Equation**: From the problem, we know: \[ r_1 - r_2 = 24 \cdot r_0 \] Therefore, we can set up the equation: \[ r_0(n1^2 - n2^2) = 24 \cdot r_0 \] Dividing both sides by \( r_0 \) (assuming \( r_0 \neq 0 \)): \[ n1^2 - n2^2 = 24 \] 5. **Factor the Difference of Squares**: The equation \( n1^2 - n2^2 = 24 \) can be factored as: \[ (n1 - n2)(n1 + n2) = 24 \] 6. **Identify Possible Integer Solutions**: We need to find pairs of integers (n1, n2) such that their product equals 24. The pairs of factors of 24 are: - (1, 24) - (2, 12) - (3, 8) - (4, 6) We can use these pairs to find possible values for \( n1 \) and \( n2 \). 7. **Test Possible Values**: We will test pairs to see if they yield valid quantum numbers: - For \( n1 - n2 = 4 \) and \( n1 + n2 = 6 \): - Solving these gives \( n1 = 5 \) and \( n2 = 1 \). - For \( n1 - n2 = 6 \) and \( n1 + n2 = 4 \): - This does not yield valid quantum numbers since \( n1 \) cannot be less than \( n2 \). - For \( n1 - n2 = 8 \) and \( n1 + n2 = 3 \): - This also does not yield valid quantum numbers. - For \( n1 - n2 = 12 \) and \( n1 + n2 = 2 \): - This does not yield valid quantum numbers. - For \( n1 - n2 = 3 \) and \( n1 + n2 = 8 \): - Solving these gives \( n1 = 5 \) and \( n2 = 7 \). 8. **Conclusion**: The possible transitions are: - From \( n1 = 5 \) to \( n2 = 1 \) - From \( n1 = 7 \) to \( n2 = 5 \) Thus, the identified transitions are \( n = 5 \to n = 1 \) and \( n = 7 \to n = 5 \).

To solve the problem of identifying the electronic transition in a hydrogen atom based on the given difference in orbit radius, we can follow these steps: ### Step-by-Step Solution: 1. **Understand the Problem**: We need to identify the transition from an initial state (n1) to a final state (n2) in a hydrogen atom, given that the difference in orbit radius (r1 - r2) is 24 times the first Bohr radius (r0). 2. **Recall the Formula for Bohr Radius**: The radius of the nth orbit in a hydrogen atom is given by the formula: \[ ...
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ALLEN-ATOMIC STRUCTURE-Exercise - 01
  1. If the value of E=-78.4 "kcal//mol", the order of the orbit in hydroge...

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  2. If velocity of an electron in 1st orbit of H atoms is V , what will b...

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  3. In a certain electronic transition in the hydrogen atoms from an init...

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  4. Match the following - {:((a),"Energy of ground state of" He^(+),(i)...

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  5. The energy of hydrogen atom in its ground state is -13.6 eV. The ener...

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  6. Total no of lines in Lyman series of H spectrum will be- (where n=n...

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  7. The spectrum of He is expected to be similar to.

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  8. What possibly can be the ratio of the de Broglie wavelength for two el...

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  9. The uncertainty in momentum of an electron is 1 xx 10^-5 kg - m//s. Th...

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  10. An alpha-"particle" is accelerated through a potential difference of V...

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  11. The orbital with zero orbital angular momentum is.

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  12. Which of the following is electronic configuration of Cu^(2+) (Z = 29)...

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  13. The electronic configuration of the Mn^(4+) ion is -

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  14. Which of the following has the maximum number of unpaired d-electron?

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  15. The total spin resulting from a d^7 configuration is :

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  16. {:("Given",K,L,M,N,),(,2,8,11,2,):} The number of electrons present ...

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  17. The configuration is 1s^(2) 2s^(2) 2p^(5) 3s^(1) shows :

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  18. The possible value of l and m for the last electron in the Cl^(- )ion ...

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  19. In which transition, one quantum of energy is emitted -

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  20. Chose the currect on the basis of Bohr's theory

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