Home
Class 12
CHEMISTRY
The pK(sp) of AgI is 16.07 if the E^(@) ...

The `pK_(sp)` of `AgI` is `16.07` if the `E^(@)` value for `Ag^(+)//Ag` is `0.7991V`, find the `E^(@)` for the half cell reaction `AgI(s) +e^(-) rarr Ag+I^(-)`

Text Solution

Verified by Experts

The correct Answer is:
`E^(@) =- 0.149V`

`E_(I^(-)//AgI//Ag)^(@) = E_(Ag^(+)//Ag)^(@) +(0.0591)/(1)log K_(sp) (AgI)`
`= 0.7991 +0.991 xx 16.07`
`rArr 0.149 V`
`(1)/(2) H_(2) rarr H^(+) +e^(-)`
Promotional Banner

Topper's Solved these Questions

  • ELECTROCHEMISTRY

    ALLEN|Exercise EXERCISE-04 [B]|23 Videos
  • ELECTROCHEMISTRY

    ALLEN|Exercise EXERCISE-05 [A]|28 Videos
  • ELECTROCHEMISTRY

    ALLEN|Exercise EXERCISE-03|24 Videos
  • CHEMISTRY AT A GLANCE

    ALLEN|Exercise ORGANIC CHEMISTRY|483 Videos
  • HYDROCARBON

    ALLEN|Exercise MCQ|15 Videos

Similar Questions

Explore conceptually related problems

Dissociation constant for Ag(NH_(3))_(2)^(+) into Ag^(+) and NH_(3) is 6 xx 10^(-14) . Calculate E^(@) for the half reaction. Ag(NH_(3))_(2)^(+) + e rarr Ag + 2NH_(3) Given, Ag^(+) + e rarr Ag has E^(@) = 0.799 V

The cell Pt(H_(2))(1atm) |H^(+) (pH =?) T^(-) (a=1)AgI(s), Ag has emf, E_(298KK) =0 . The electrode potaneial for the reaction AgI +e^(-) rarr Ag + I^(Theta) is -0.151 volt. Calculate the pH value:-

K_(d) for dissociation of [Ag(NH_(3))_(2)]^(+) into Ag^(+) and NH_(3) is 6 xx 10^(-8) . Calculae E^(@) for the following half reaction. AG(NH_(3))_(2)^(+) +e^(-) rarr Ag +2NH_(3) Given Ag^(+) +e^(-) rarr Ag, E^(@) = 7.99V

The K_(sp) for AgCl at 298 K is 1.0xx10^(-10) . Calculate E for Ag^(+)//Ag electrode immersed in 1.0 M KCl solution. Given : E^(@)Ag^(+)//Ag=0.799" V" .

ALLEN-ELECTROCHEMISTRY-EXERCISE-04 [A]
  1. The emf of the cell Ag|KI(0.05M)||AgNO(3)(0.05M)|Ag is 0.788V. Calcula...

    Text Solution

    |

  2. The cell Pt, H(2) (1atm) H^(+) (pH =x)| Normal calomel Electrode has a...

    Text Solution

    |

  3. Estimate the cell potential of a Daniel cell having 1.0 M Zn^(++) and ...

    Text Solution

    |

  4. Consider the cell AG|AgBr(s)|Br^(-)||AgCI(s)|CI^(-)|Ag at 25^(@)C. The...

    Text Solution

    |

  5. The pK(sp) of AgI is 16.07 if the E^(@) value for Ag^(+)//Ag is 0.7991...

    Text Solution

    |

  6. Voltage of the cell Pt, H(2) (1atm)|HOCN(1.3 xx 10^(-3)M)||Ag^(+) (0....

    Text Solution

    |

  7. The standard oxidation potential of Zn referred to SHE is 0.76V and th...

    Text Solution

    |

  8. The standard reduction potential E^(@)(Bi^(3+)//Bi) and E^(@)(Cu^(2+)/...

    Text Solution

    |

  9. Calculate the potential of an indicator electrode versus the standard ...

    Text Solution

    |

  10. K(d) for dissociation of [Ag(NH(3))(2)]^(+) into Ag^(+) and NH(3) is 6...

    Text Solution

    |

  11. The overall formation constant for the reaction of 6 mole of CN^(-) wi...

    Text Solution

    |

  12. Calculate the e.m.f. of the cell Pt|H(2)(1.0atm)|CH(3)COOH (0.1M)||N...

    Text Solution

    |

  13. An external current source giving a current of 5.0A was joined with Da...

    Text Solution

    |

  14. Calculate the equilibrium constant for the reaction: 3Sn(s) +2Cr(2)O...

    Text Solution

    |

  15. Calculate the voltage E of the cell at 25^(@)C Mn(s) |Mn(OH(2))(s)|M...

    Text Solution

    |

  16. Calculate the voltage E of the cell Ag(s)| AgIO(3)(s)|Ag^(+) (x,M), ...

    Text Solution

    |

  17. The voltage of the cell Pb(s)|PbSO(4)(s)|NaHSO(4)(0.600M)||Pb^(2+)(2...

    Text Solution

    |

  18. The voltage of the cell Zn(s)|Zn(CN)(4)^(2-) (0.450M),CN^(-) (2.65 x...

    Text Solution

    |

  19. A 500mL sample of a 0.1M Cr^(3+) is electrolyzed with a current of 96....

    Text Solution

    |

  20. {:(Content,Resistance ,"Volume of gas produced"),(,(at same T & P),),(...

    Text Solution

    |