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An acid base indicator has K(a)=1.0xx10^...

An acid base indicator has `K_(a)=1.0xx10^(-5)` the acid form of the indicator is red and the bais form is blue. Calculate the pH change required to change the colour of the indicator from 80% red to 80% blue.

A

1.2

B

0.8

C

0.2

D

1.4

Text Solution

Verified by Experts

The correct Answer is:
A

for the indicator `HlnhArrH^(+)+ln^(-)`
According to the question, 20% of the final form of the indicator is blue (acidic) and 80% red (basic).
`K_(ln)=([H^(+)][ln^(-)])/([Hln])`
`[H^(+)]=K_(ln)([ln^(-)])/([Hln])=1xx10^(-5)((80)/(20))=4xx10^(-5)`
`pH=4.4`
80% blue `[H^(+)]=1xx10^(-5)((20)/(80))`
`pH=6-0.4=5.6`
`therefore` change in `pH=5.6-4.4=1.2`
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