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A certain amount of reducing agent reduc...

A certain amount of reducing agent reduces x mole of `KMnO_(4)` & y mole of `K_(2)Cr_(2)O_(7)` in difference experiments in acidic medium. If the change in oxidation state of reducing agent is same in both experiments then `x:y` is

A

`5:3`

B

`3:5`

C

`5:6`

D

`6:5`

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The correct Answer is:
To solve the problem, we need to analyze the reduction of potassium permanganate (KMnO4) and potassium dichromate (K2Cr2O7) by a reducing agent in acidic medium. We are given that the change in oxidation state of the reducing agent is the same in both experiments. ### Step-by-Step Solution: 1. **Understanding the Reaction**: - In acidic medium, KMnO4 is reduced from Mn(VII) to Mn(II), which involves a change in oxidation state of 5. - K2Cr2O7 is reduced from Cr(VI) to Cr(III), which involves a change in oxidation state of 3. 2. **Equivalence of Reducing Agents**: - The number of equivalents of KMnO4 reduced can be calculated as: \[ \text{Equivalents of KMnO4} = 5x \] where \(x\) is the number of moles of KMnO4. - The number of equivalents of K2Cr2O7 reduced can be calculated as: \[ \text{Equivalents of K2Cr2O7} = 6y \] where \(y\) is the number of moles of K2Cr2O7. 3. **Setting Up the Equation**: - Since the change in oxidation state of the reducing agent is the same in both experiments, we can equate the equivalents: \[ 5x = 6y \] 4. **Finding the Ratio \(x:y\)**: - Rearranging the equation gives: \[ \frac{x}{y} = \frac{6}{5} \] - Therefore, the ratio \(x:y\) is: \[ x:y = 6:5 \] ### Final Answer: The ratio \(x:y\) is \(6:5\).

To solve the problem, we need to analyze the reduction of potassium permanganate (KMnO4) and potassium dichromate (K2Cr2O7) by a reducing agent in acidic medium. We are given that the change in oxidation state of the reducing agent is the same in both experiments. ### Step-by-Step Solution: 1. **Understanding the Reaction**: - In acidic medium, KMnO4 is reduced from Mn(VII) to Mn(II), which involves a change in oxidation state of 5. - K2Cr2O7 is reduced from Cr(VI) to Cr(III), which involves a change in oxidation state of 3. ...
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