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The activation energies of two reactions...

The activation energies of two reactions are `E_(1)` & `E_(2)` with `E_(1)gtE_(2)`. If temperature of reacting system is increased from `T_(1)` (rate constant are `k_(1)` and `k_(2)`) to `T_(2)` (rate constant are `k_(1)^(1)` and `k_(2)^(1)`) predict which of the following alternative is incorrect.

A

`(k_(1)^(1))/(k_(1))=(k_(2)^(1))/(k_(2))`

B

`(k_(1)^(1))/(k_(1))gt(k_(2)^(1))/(k_(2))`

C

`(k_(1)^(1))/(k_(1))lt(k_(2)^(1))/(k_(2))`

D

`k_(1)^(1)ltk_(2)^(1)`

Text Solution

Verified by Experts

The correct Answer is:
B

Greater the activation energy of a reaction, greater is the temperature dependence of rate constant of reaction.
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