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The wavelength of the first Lyman lines ...

The wavelength of the first Lyman lines of hydrogen `He^(+)` and `Li^(2+)` ions and `lamda_(1),lamda_(2)& lamda_(3)` the ratio of these wavelengths is

A

`1:4:9`

B

`9:4:1`

C

`36:9:4`

D

`6:3:2`

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The correct Answer is:
To solve the problem of finding the ratio of the wavelengths of the first Lyman lines for hydrogen (H), helium ion (He⁺), and lithium ion (Li²⁺), we will use the Rydberg formula for the wavelengths of spectral lines in hydrogen-like atoms. ### Step-by-Step Solution: 1. **Identify the Transition**: The first Lyman line corresponds to the transition from n=2 to n=1. Thus, we will consider the transitions for each ion: - For hydrogen (H): n1 = 1, n2 = 2 - For helium ion (He⁺): n1 = 1, n2 = 2 - For lithium ion (Li²⁺): n1 = 1, n2 = 2 2. **Rydberg Formula**: The Rydberg formula for the wavelength (λ) of a spectral line is given by: \[ \frac{1}{\lambda} = RZ^2 \left( \frac{1}{n_1^2} - \frac{1}{n_2^2} \right) \] where: - \( R \) is the Rydberg constant, - \( Z \) is the atomic number, - \( n_1 \) and \( n_2 \) are the principal quantum numbers. 3. **Calculate for Each Ion**: - **For Hydrogen (H)**: \[ \frac{1}{\lambda_1} = R \cdot 1^2 \left( \frac{1}{1^2} - \frac{1}{2^2} \right) = R \left( 1 - \frac{1}{4} \right) = R \cdot \frac{3}{4} \] Thus, \( \lambda_1 = \frac{4}{3R} \). - **For Helium Ion (He⁺)**: \[ \frac{1}{\lambda_2} = R \cdot 2^2 \left( \frac{1}{1^2} - \frac{1}{2^2} \right) = R \cdot 4 \left( 1 - \frac{1}{4} \right) = R \cdot 4 \cdot \frac{3}{4} = 3R \] Thus, \( \lambda_2 = \frac{1}{3R} \). - **For Lithium Ion (Li²⁺)**: \[ \frac{1}{\lambda_3} = R \cdot 3^2 \left( \frac{1}{1^2} - \frac{1}{2^2} \right) = R \cdot 9 \left( 1 - \frac{1}{4} \right) = R \cdot 9 \cdot \frac{3}{4} = \frac{27R}{4} \] Thus, \( \lambda_3 = \frac{4}{27R} \). 4. **Finding the Ratios**: Now we can find the ratios of the wavelengths: \[ \text{Ratio} = \frac{\lambda_1 : \lambda_2 : \lambda_3} = \frac{\frac{4}{3R} : \frac{1}{3R} : \frac{4}{27R}}{1} = \frac{4 : 1 : \frac{4}{27}}{1} \] To simplify, multiply through by 27: \[ = 4 \cdot 27 : 1 \cdot 27 : 4 = 108 : 27 : 4 \] Thus, the final ratio is: \[ = 108 : 27 : 4 \] ### Final Answer: The ratio of the wavelengths \( \lambda_1 : \lambda_2 : \lambda_3 \) is \( 108 : 27 : 4 \).

To solve the problem of finding the ratio of the wavelengths of the first Lyman lines for hydrogen (H), helium ion (He⁺), and lithium ion (Li²⁺), we will use the Rydberg formula for the wavelengths of spectral lines in hydrogen-like atoms. ### Step-by-Step Solution: 1. **Identify the Transition**: The first Lyman line corresponds to the transition from n=2 to n=1. Thus, we will consider the transitions for each ion: - For hydrogen (H): n1 = 1, n2 = 2 - For helium ion (He⁺): n1 = 1, n2 = 2 ...
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