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How is the variablility in oxidation st...

How is the variablility in oxidation states of transition metals different from that of the non transition metals gt illustrate with example

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The variability in oxidation state of trasnsition is due to the incomplete filling of d-orbitals in such a way that their oxidation states differ from each other by unity e.g., Fe^(2+)` and `Fe^(3+)` Cu^(+) and Cu^(2+)` etc. In case of non -transition elements , the oxidation state differ by units of two ,e.g., `pb^(2+)`, and `Sn^(2+)` and `Sn^(4+)` etc. Moreover , in transition elements ,t he higher oxidation states are more stable for heavier elements in a group. For example, in group6 `Mp(VI)` and `W(VI)` are more stable than `Cr(VI)` . In p-block elements , the lower oxidation state are more stable for heavier members due to inert pair effect,e.g., in group 14 , `pb(II) is more stable than pb(IV)`
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Knowledge Check

  • Transition metals from

    A
    Ionic bonds
    B
    Ionic, covalent and coordinate covalent bonds
    C
    Covalent bonds
    D
    Vordinate covalent bonds
  • In which pair highest oxidation states of transition metals are found

    A
    nitriles and chlorides
    B
    fluorides and chlorides
    C
    fluorides and oxides
    D
    nitriles and oxides
  • Lower oxidation state in transition metals are stabilized by

    A
    CO
    B
    O
    C
    I
    D
    Br
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