Home
Class 12
CHEMISTRY
What may be the stable oxidation state o...

What may be the stable oxidation state of the transition elements with the following d electron configurations in the ground state of their atoms:`3d^(3),3d^(5),3d^(4)?`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the stable oxidation states of transition elements with the given d electron configurations (3d^3, 3d^5, and 3d^4), we can analyze each configuration step by step. ### Step 1: Identify the Transition Element for Each Configuration - **3d^3**: This configuration corresponds to the element Vanadium (V). - **3d^5**: This configuration corresponds to the element Manganese (Mn). - **3d^4**: There is no stable transition metal with this exact configuration in its ground state. The closest stable configuration is for Chromium (Cr), which has a configuration of 3d^5 4s^1. ### Step 2: Determine the Stable Oxidation States - **For 3d^3 (Vanadium)**: - Vanadium can lose its 3d electrons and 4s electrons to form oxidation states. - Possible oxidation states: +2, +3, +4, +5. - The most stable oxidation states are typically +3 and +5. - **For 3d^5 (Manganese)**: - Manganese can also lose its 3d and 4s electrons. - Possible oxidation states: +2, +4, +6, +7. - The most stable oxidation states are +2, +4, +6, and +7, with +7 being the maximum. - **For 3d^4**: - As mentioned, there is no transition metal with a stable ground state configuration of 3d^4. The closest is Chromium (3d^5 4s^1). - For Chromium, the oxidation states are +2, +3, +6, with +3 being the most stable. ### Summary of Stable Oxidation States - **3d^3 (Vanadium)**: +2, +3, +4, +5 (most stable: +3, +5) - **3d^5 (Manganese)**: +2, +4, +6, +7 (most stable: +2, +4, +6, +7) - **3d^4**: No stable transition metal corresponds to this configuration.
Promotional Banner

Topper's Solved these Questions

  • D BLOCK ELEMENTS

    RESONANCE|Exercise EXERCISE-2 PART-II|52 Videos
  • D BLOCK ELEMENTS

    RESONANCE|Exercise EXERCISE-2 PART-IV|7 Videos
  • D BLOCK ELEMENTS

    RESONANCE|Exercise EXERCISE-I PART-III|15 Videos
  • D & F BLOCK ELEMENTS

    RESONANCE|Exercise INORGANIC CHEMISTRY(d & f- Block Elments)|40 Videos
  • DPP

    RESONANCE|Exercise QUESTIONS|223 Videos

Similar Questions

Explore conceptually related problems

What may be the stable oxidation state of the transition element with the following d electron configurations in the ground state of their atoms : 3d^(3),3d^(5),3d^(8) and 3d^(4) ?

What may the possible oxidation state of transition metals with the following electronic configurations in the ground state of their atoms ? (i) 3d^(3)4s^(2) (ii) 3d^(5)4s^(2) (iii) 3d^(6)4s^(2) .

The outer electronic configuration of the ground state chromium atom is 3d^(2),4s^(2)

The most common oxidation states of 3d series elements

The element with electronic configuration 3d^(5)4s^(1) is

RESONANCE-D BLOCK ELEMENTS-EXERCISE-2 PART-I
  1. Between Na^(+) and Ag^(+) , which is stronger Lewis acid and why?

    Text Solution

    |

  2. Why the highest oxidations state of a metal is exhibited in its or flu...

    Text Solution

    |

  3. What may be the stable oxidation state of the transition elements with...

    Text Solution

    |

  4. Why arre Mn^(2+) compounds more stable than Fe^(2+) toward oxidation t...

    Text Solution

    |

  5. How is the variability in oxidation states fo transition metals differ...

    Text Solution

    |

  6. which metal in the first series of transition metals exhibits +1 oxid...

    Text Solution

    |

  7. The E(Theta)(M^(2+)//M) Value for copper is positive (+0.34V) . What i...

    Text Solution

    |

  8. Why is the E^(Theta) value for the Mn^(3+)//Mn^(2+) couple much postiv...

    Text Solution

    |

  9. Which is a stronger reducing agent Cr^(2+) or Fe^(2+) and why?

    Text Solution

    |

  10. Why is Cu^(+) ion not stable in aqueous solution ? or Why is Cu^(+...

    Text Solution

    |

  11. The aqueous solution of FeCl(3) is acidic . Why?

    Text Solution

    |

  12. Ferric iodide is very unstable but ferric chloride is not

    Text Solution

    |

  13. Copper dissolves in dilute nitrate acid but not in dilute HCl. Why?

    Text Solution

    |

  14. Blue colour of CUSO(4) solution is discharge slowly when an iron rod i...

    Text Solution

    |

  15. Copper (I) Salts are not known in aueous solution.

    Text Solution

    |

  16. Calculate the number of unpaired electrons in the following gaseous io...

    Text Solution

    |

  17. Mercurous ion is written as Hg(2)^(2+) whereas cuprous ion is written ...

    Text Solution

    |

  18. Copper sulphate dissolves in Nh(4)OH solution but FesO(4) does not.

    Text Solution

    |

  19. An aqueous solution of inorganic compounds (X) gives following reactio...

    Text Solution

    |

  20. H(2)S gas is passed through an acidic solution of K(2)Cr(2)O(7) . The ...

    Text Solution

    |