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The radii (metallic) of Fe,CO and Ni are...

The radii (metallic) of `Fe,CO and Ni` are nearly same.
This is due to:

A

Lanthanide contraction

B

The fact that successive addition of d-electrons screens (4s) from the inward pull of the nucleus.

C

increase in radii due to increase in `n` is compensated by decrease in radii due to increase in effctive nulcear charge(Z).

D

Atomic radii do not remain constant but increase in a normal gradation.

Text Solution

Verified by Experts

The correct Answer is:
B

After mid way i.e. after `Cr` as the electrons enters the last but one shell, the added d-electron shield the outer most electrons. Hence with the increase in the d-electron screening effect increase . This counter balance the increased nuclear charge. As a result , the atomic radii remain practically same after chromium.
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RESONANCE-D BLOCK ELEMENTS-EXERCISE-2 PART-II
  1. The correct ground state electronic configuration of chromium atom(Z=2...

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  2. Transition metals:

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  3. The radii (metallic) of Fe,CO and Ni are nearly same. This is due to...

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  4. Atomic of the transition elements than those of the s-block elements ...

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  5. Which of the following factor may be regarded as the main cause of lan...

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  6. Which of the following transition metal ions has the lowest density?

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  7. Of the ions Zn^(2+),Ni^(2+) and Cr^(3+) (atomic number Zn=30,Ni=28,Cr=...

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  8. Among the following pairs of ions the lower oxidation state in aqueous...

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  9. VO(2) is an amphoteric oxide and in acidic medium it form:

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  10. Which of the following transition metal shows the highest oxidation st...

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  11. Standard reduction electrode potential of Zn^(2+)//Zn is -0.76V. This ...

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  12. E^(Theta) value for the couple Cr^(3+)//Cr^(2+) and Mn^(3+)//Mn^(2+) a...

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  13. Which one of the following show highest magnetic moment?

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  14. Amongest the following the lowest degree of paramagnetism per mole of ...

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  15. Which one of the transittion metal ions is coloured in aqueous solutio...

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  16. Compound that is both paramagnetic and coloured is:

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  17. Which of the following is expected to be coloured?

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  18. Most transition metals:(I) Form sets of compounds which display differ...

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  19. The aqueous solution of the following salts will be coloured in the ca...

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  20. Which one of the following characteristics of the transition metals is...

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