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Consider the following statements : st...

Consider the following statements :
statement-1: `[Cr(NH_(3))_(6)]^(3+)]^(3+)` is an inner orbital complex with crystal field stabilization energy complex with crystal field stabilization energy equal to -1.2 `Delta_(0)`.
Statement -2: The complex formed by joining the `CN^(-)` ligands to `Fe^(3+)` ion has theoretical value of 'spin only' magnetic moment equal to 1.73 BM.
Statement-3: `Na_(2)S+Na_(2) [Fe(CN)_(5)NO] to Na_(4)[Fe(CN)_(5)NOS]`, In reactant and product the oxidation states of iron are same and arrange in the order of true/false.

A

FTF

B

TTF

C

TTT

D

FFF

Text Solution

Verified by Experts

The correct Answer is:
C

`[Cr(NH_(3))_(6)]^(3+) implies d^(3) , t_(2 g )^( 2 ,2 , 1) eg^(0 , 0)`
CFSE = `-0.4 xx 3 Delta_(0) = -1.2 Delta_(0)`.
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S-1 : [Cr(NH_(3))_(6)]^(3+) is a inner orbital complex with S-2: The complex formed by joining the CN ligands to Fe^(3+) ion has theoretical value fo 'spin only' magnetic moment equal to 1.73 B.M. S-3: Na_(2)S+Na_(2)[Fe(CN)_(5)NO]rarrNa_(4)[Fe(CN)_(5)NOS], In reactan and product the oxidation states of iron are same

What is the value of spin only magnetic moment of anionic and cationic part of complex [Fe(H_(2)O)_(6)]_(2) [Fe(CN)_(6)]

In Na_(2)[Fe(CN)_(5)NO] , sodium nitroprusside:

Na_(2)S+Na_(2)[Fe(CN)_(5)NO]rarrNa_(4)[Fe(NH)_(5)nos], oxidation number of Fe in reactant ( complex ) and product ( complex) are :

The complex Na_(2)[Fe(CN)_(5)NO] is called :

OP TANDON-COORDINATION COMPOUNDS-D.VBT, CFT, Hybridisation
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  2. Which one of the following has a square planar geometry ? [At. no. Co=...

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  3. Consider the following statements : statement-1: [Cr(NH(3))(6)]^(3+)...

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  4. In which of the following octahedral complexes of Co(at. no. 27), will...

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  5. Among [Ni(CN)(4)]^(4-), [Ni(PPh(3))(3)Br] and [Ni(dmg)(2)] species, th...

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  6. The value of 'spin only' magnetic moment for one of the following conf...

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  7. Which of the following has dsp^(2) hybridization and is diamagnetic in...

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  8. Which one is an outer orbital complex ?

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  9. The geometry of [NiCl(4)]^(2-) and [NiCl(2)(Pme(3))(2)] are :

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  10. The geometry ion which hs no d electrons in the central metal atom is ...

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  11. The species having tetrahedral shape is :

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  12. Which one of the following high-spin complexes has the largest CFSE (C...

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  13. The hybridization of [CoF(6)]^(3-) and [Co(C(2)O(4))}^(3-) are :

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  14. The total crystal field stabilization energy (CFSE) for the complexes ...

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  15. Wilkinson's catalyst react with H(2) to form an octahedral complex in ...

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  16. The 'spin only' magnetic moment (in units of Bohr magneton, mu(B)) of ...

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  17. K(6)[(CN)(5) Co-O-O-Co(CN)(5)]overset("oxidised")to (X) K(5)[(CN)(5)Co...

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  18. The coordination number and the oxidation state of element E in the co...

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  19. Which of the following is not correctly matched ?

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  20. The complex K(4)[Zn(CN)(4)(O(2))(2)] is oxidised into K(2)[Zn(CN)(4)(O...

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