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Statement-1: [Fe(H(2)O)(5)NO]SO(4) is pa...

Statement-1: `[Fe(H_(2)O)_(5)NO]SO_(4)` is paramagnetic.
Statement-2: The Fe in `[Fe(H_(2)O)_(5)NO]SO_(4)` has three unpaired electrons.

A

Statement-1 is True, Statement-2 is True , Statement-2 is a correct explanation for Statement-1.

B

Statement-1 is True, Statement-2 is True, Statement-2 is NOT a correct explanation for Statement-1.

C

Statement-1 is True, Statement-2 is False.

D

Statement-1 is False, Statement-2 is True.

Text Solution

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The correct Answer is:
A
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Statement I [Fe(H_(2)O)_(5)NO]SO_(4) is paramagnetic Statement II The Fe in [Fe(H_(2)O)_(5)NO]SO_(4) has three unpaired electrons .

The question consist of two statements each, printed as Assertion and Reason. While answering these questions you are required to choose any one of the following four responses: Assertion: [Fe(H_2O)_5NO]SO_4 is paramagnetic. Reason: The Fe in [Fe(H_2O)_5NO]SO_4 has three unpaired electrons.

(a). Assertion (A) is true, Reason (R) is also true, Reason (R) is the correct explanation for assertion (A). (b). Assertion (A) is true, Reason (R) is true, Reason (R) is not the correct explanation for Assertion (A). (c). Assertion (A) is true, Reason (R) is false. (d). Assertion (A) is false, Reason (R) is true. Q. Assertion (A): [Fe(H_2O)_5NO]SO_4 paramagnetic. Reason (R): The Fe in [Fe(H_2O)_5NO]SO_4 has three unpaired electrons.

The oxidation state of Fe in brown complex [Fe(H_(2)O)_(5)NO]SO_(4) is

Assertion : [Fe(H_(2)O)_(6)]^(2+) is sp^(3) d^(2) hybridised and paramagnetic complex ion . Reason : [Fe(H_(2)O)_(6)]^(2+) has four unpaired electrons as H_(2)O is a weak field ligand .

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