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The Arrhenious equation for the decompos...

The Arrhenious equation for the decomposition of methyl nitrite and ethyl nitride are `k_(1)` and `k_(2)` respectively and the activation energy of second is `4 kJ//"mole"` is more than that of first. At what temperature value of rate constant `k_(1)` will be equal to `k_(2)` if
`k_(1) (s) = 10^(13) (e^(-(E_(a_(1)))/(RT)))` and `k_(2)(s^(-1)) = 10^(14) (e^(-(E_(a_(2)))/(RT)))`

A

`650 K`

B

`230 K`

C

`325 K`

D

`425 K`

Text Solution

Verified by Experts

The correct Answer is:
B

`10^(13)e^(-(Ea_(1))/(RT)) = 10^(14)e^(-(Ea_(2))/(RT)`
`T = 230K`
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The Arrehenius equation for the rate constant of decompoistion of methyl nitrite and ethyl nitrite are k_(1) (s^(-1)) =10^(13) exp ((-152300 J mol^(-1))/(RT)) and k_(2)(s^(-1)) = 10^(14)exp((-157700 J mol^(-1))/(RT)) respectively. Find the temperature at which the rate constant are equal.

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