Home
Class 11
CHEMISTRY
If n(1) and n(2) are the boundary value ...

If `n_(1)` and `n_(2)` are the boundary value principal quantum numbers of a portion fo spectrum of emission spectrum of `H` atom, determine the wavelength ( in metre ) corresponding to last line ( longest `lambda)` . Given `:n_(1) + n_(2) =7, n_(2)-n_(1)=3` and `R_(H)=1.097xx10^(7)m^(-1)` . ( Give your answer in multiple of `10^(-6))`

A

8

B

4

C

10

D

15

Text Solution

Verified by Experts

The correct Answer is:
2

Here `n_(2)=5 & n_(1)=2`
So longest wavelength means least energy difference transition `i.e. n_(2)=5` to `n_(1)=4`
`(1)/(lambda)=R_(H)(1)^(2)((1)/((4)^(2))-(1)/((5)^(2)))`
So `lambda=4xx10^(-6)m`
Promotional Banner

Topper's Solved these Questions

  • AROMATIC COMPOUNDS

    RESONANCE|Exercise PART-II : JEE (MAIN)|1 Videos
  • CHEMICAL BONDING

    RESONANCE|Exercise Inorganic chemistry (Chemistry Bonding)|49 Videos

Similar Questions

Explore conceptually related problems

Values of n_(1) and n_(2) for H_(b) spectral line in the hydrogen emission spectrum

In hydrogen spectrum wave number of different lines is given by 1/lambda=R_(H)[1/n_(i)^(2)-1/n_(f)^(2)] where R_(H)=1.090678xx10^(7)m^(-1) The wavelength of first line of Lyman series would be

In a sample of H like atoms highest quantum state is n = 6. Find total number of spectral lines in emission spectrum

Using Bohr's formula for energy quantisation, determine (i) the largest wavelength in Balmer series of hydrogen atom spectrum and (ii) the excitation energy of n = 3 level of He^(+) ion. Given R = 1.097 xx 10^(7) m^(-1)

The wavelength of a certain line in the Pashchen series is 1093.6nm . What is the value of n_(high) for this line [R_(H)=1.0973xx10^(-7)m^(-1)]

Find the two longest wavelength ("in" Å) emitted when hydrogen atom make transition and the spectrum lines lie in the visible regain (R = 1.097 xx 10^(7) m^(-1))

The value of n for a line Balmer series of hydorgen spectrum having the highest wave length is 4 and 6 . For Balmer series of hydorgen spectrum, the value n_1 = 2 and n_2 = 3, 4, 5 .

The electron in a H- atom makes a transition from n_(1) to n_(2) where n_(1) and n_(2) are the principal quantum number of the states. Assume Bohr's model to be valid. The time period of the electron in initial state is 27 times that in final state Find the possible value of n_(1) and n_(2) if only just first 10 states are in the visible range of instrument.

The wave number of the first emission line in the Balmer series of H - Spectrum is (n)/(36)R . The value of 'n' is. (R = Rydberg constant):

RESONANCE-ATOMIC STRUCTURE-PHYSICAL CHEMISTRY(ATOMIC EQUILIBRIUM)
  1. psi^(2)=0 represent

    Text Solution

    |

  2. Observer the following statements regarding isotones : a. .^(39)K an...

    Text Solution

    |

  3. If n(1) and n(2) are the boundary value principal quantum numbers of a...

    Text Solution

    |

  4. What is the potential energy of an electron present in N- shell of th...

    Text Solution

    |

  5. In which of the following transition, the wavelength will be minimum ...

    Text Solution

    |

  6. The ratio of kinetic energy and potential energy of an electron in a B...

    Text Solution

    |

  7. Total Number of unpaired electrons in d- orbitals of an atom element o...

    Text Solution

    |

  8. Photons of minimum energy 496k,J. mol^(-1) are needed to an atoms. Cal...

    Text Solution

    |

  9. According to Bohr's model, if the kinetic energy of an electron in 2^(...

    Text Solution

    |

  10. Last line of Lyman series for H- atom has wavelength lambda(1) A,2^(nd...

    Text Solution

    |

  11. Which electronic level would allow the hydrogen atom to absorbs a phot...

    Text Solution

    |

  12. Number of nomal planes ( planes of zero electron densit ) in the d(xy)...

    Text Solution

    |

  13. The uncertainty in position and velocity of the particle are 0.2mm and...

    Text Solution

    |

  14. A particle initially at rest having charge q coulomb, & mass m kg i...

    Text Solution

    |

  15. The number of possible lines of Paschenc series when electron jumps fr...

    Text Solution

    |

  16. AIR service on Vividh Bharati is transmitted on 219m band. What is its...

    Text Solution

    |

  17. Calculate the maximum and minimum number of electrons. Which may have ...

    Text Solution

    |

  18. In the emission spectrum of H- atom from energy level 'n' to ground s...

    Text Solution

    |

  19. The ionisation energy of H is 13.6 eV. Calculate the ionization energy...

    Text Solution

    |

  20. If Photon having wavelength 6.2nmwas allowed to strike a metal plate h...

    Text Solution

    |