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For the following equilibrium, 2SO(2)(g)...

For the following equilibrium, `2SO_(2)(g) +O_(2)(g) hArr 2SO_(3)(g)` the total equilibrium pressure is `P_(1)`. If volume of the system is reduced to `1//2` of this initial volume then equilibrium is restablished. The new equilibrium total pressure will be `:`

A

`2P_(1)`

B

`3P_(1)`

C

`3.5P_(1)`

D

less than `2P_(1)`

Text Solution

Verified by Experts

The correct Answer is:
4
`{:(,2SO_(2)(g),+,O_(2)(g),hArr,2SO_(3)(g)),("at Eq",x,,y,,z),("on reducing vol",2x,,2y,,2z),("new Eq.",2x-2a,,2y-a,,2z-2a),("total pressure",=2(x+y+z)-a,=2P_(1)-a,,,lt2P_(1)):}`
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