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For the reaction : " "2A+B hArr 3C ...

For the reaction `:` `" "2A+B hArr 3C` at `298 K, K_(c)=49`
A `3L` vessel contains 2,1 and 3 molesof `A, B` and `C` respectively.
The reaction at the same temperature

A

must proceed in forward direction

B

must proceed in backward direction

C

must be in equilibrium

D

cannot be predicted

Text Solution

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The correct Answer is:
To solve the problem, we need to determine the direction of the reaction based on the given concentrations of reactants and products, and compare the reaction quotient \( Q_c \) with the equilibrium constant \( K_c \). ### Step-by-Step Solution: 1. **Identify the Reaction and Given Data:** The reaction is: \[ 2A + B \rightleftharpoons 3C \] Given: - \( K_c = 49 \) - Moles of \( A = 2 \) - Moles of \( B = 1 \) - Moles of \( C = 3 \) - Volume of the vessel = 3 L 2. **Calculate the Concentrations:** To find the concentrations of each species, we use the formula: \[ \text{Concentration} = \frac{\text{Number of moles}}{\text{Volume in liters}} \] - Concentration of \( A \): \[ [A] = \frac{2 \text{ moles}}{3 \text{ L}} = \frac{2}{3} \text{ M} \] - Concentration of \( B \): \[ [B] = \frac{1 \text{ mole}}{3 \text{ L}} = \frac{1}{3} \text{ M} \] - Concentration of \( C \): \[ [C] = \frac{3 \text{ moles}}{3 \text{ L}} = 1 \text{ M} \] 3. **Calculate the Reaction Quotient \( Q_c \):** The expression for \( Q_c \) for the reaction is: \[ Q_c = \frac{[C]^3}{[A]^2[B]} \] Substituting the concentrations: \[ Q_c = \frac{(1)^3}{\left(\frac{2}{3}\right)^2 \left(\frac{1}{3}\right)} \] Simplifying: \[ Q_c = \frac{1}{\left(\frac{4}{9}\right) \left(\frac{1}{3}\right)} = \frac{1}{\frac{4}{27}} = \frac{27}{4} = 6.75 \] 4. **Compare \( Q_c \) with \( K_c \):** We have: - \( Q_c = 6.75 \) - \( K_c = 49 \) Since \( Q_c < K_c \), the reaction will proceed in the forward direction to reach equilibrium. 5. **Conclusion:** The reaction will shift to the right (forward direction) to form more products. ### Final Answer: The reaction will proceed in the forward direction. ---

To solve the problem, we need to determine the direction of the reaction based on the given concentrations of reactants and products, and compare the reaction quotient \( Q_c \) with the equilibrium constant \( K_c \). ### Step-by-Step Solution: 1. **Identify the Reaction and Given Data:** The reaction is: \[ 2A + B \rightleftharpoons 3C ...
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