For the reaction `:` `" "2A+B hArr 3C` at `298 K, K_(c)=49` A `3L` vessel contains 2,1 and 3 molesof `A, B` and `C` respectively. The reaction at the same temperature
A
must proceed in forward direction
B
must proceed in backward direction
C
must be in equilibrium
D
cannot be predicted
Text Solution
AI Generated Solution
The correct Answer is:
To solve the problem, we need to determine the direction of the reaction based on the given concentrations of reactants and products, and compare the reaction quotient \( Q_c \) with the equilibrium constant \( K_c \).
### Step-by-Step Solution:
1. **Identify the Reaction and Given Data:**
The reaction is:
\[
2A + B \rightleftharpoons 3C
\]
Given:
- \( K_c = 49 \)
- Moles of \( A = 2 \)
- Moles of \( B = 1 \)
- Moles of \( C = 3 \)
- Volume of the vessel = 3 L
2. **Calculate the Concentrations:**
To find the concentrations of each species, we use the formula:
\[
\text{Concentration} = \frac{\text{Number of moles}}{\text{Volume in liters}}
\]
- Concentration of \( A \):
\[
[A] = \frac{2 \text{ moles}}{3 \text{ L}} = \frac{2}{3} \text{ M}
\]
- Concentration of \( B \):
\[
[B] = \frac{1 \text{ mole}}{3 \text{ L}} = \frac{1}{3} \text{ M}
\]
- Concentration of \( C \):
\[
[C] = \frac{3 \text{ moles}}{3 \text{ L}} = 1 \text{ M}
\]
3. **Calculate the Reaction Quotient \( Q_c \):**
The expression for \( Q_c \) for the reaction is:
\[
Q_c = \frac{[C]^3}{[A]^2[B]}
\]
Substituting the concentrations:
\[
Q_c = \frac{(1)^3}{\left(\frac{2}{3}\right)^2 \left(\frac{1}{3}\right)}
\]
Simplifying:
\[
Q_c = \frac{1}{\left(\frac{4}{9}\right) \left(\frac{1}{3}\right)} = \frac{1}{\frac{4}{27}} = \frac{27}{4} = 6.75
\]
4. **Compare \( Q_c \) with \( K_c \):**
We have:
- \( Q_c = 6.75 \)
- \( K_c = 49 \)
Since \( Q_c < K_c \), the reaction will proceed in the forward direction to reach equilibrium.
5. **Conclusion:**
The reaction will shift to the right (forward direction) to form more products.
### Final Answer:
The reaction will proceed in the forward direction.
---
To solve the problem, we need to determine the direction of the reaction based on the given concentrations of reactants and products, and compare the reaction quotient \( Q_c \) with the equilibrium constant \( K_c \).
### Step-by-Step Solution:
1. **Identify the Reaction and Given Data:**
The reaction is:
\[
2A + B \rightleftharpoons 3C
...
Mass action ratio or reaction quotient Q for a reaction can be calculated using the law of mass actionl, A(g)+B(g)hArrC(g)+D(g) Q=([C][D])/([A][B]) The value of Q decides whether the reaction is at equilibrium or not. At equilibrium, Q=K For non-equilibrium process QneK When QgtK , reaction will be favoured in backward direction and when QltK , it will be favoured in forward direction. For the reaction : 2A+BhArr3C at 298 K, K_(c)=49 A 3 L vessel contains 2, 1 and 3 moles of A, B and C respectively. The reaction at the same temperature :
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