Two solid compounds X and Y dissociates at a certain temperature as follows `X(s) hArr A(g)+2B(g),K_(p1)=9xx10^(-3)atm^(3)` `Y(s) hArr 2B(g)+C(g),K_(p2)=4.5xx10^(-3)atm^(3)` The total pressure of gases over a mixture of X and Y is `:`
A
`4.5 atm`
B
`0.45 atm`
C
`0.6 atm`
D
None of these
Text Solution
Verified by Experts
The correct Answer is:
B
Let x is partial pressure of `A` and y is partial pressure of C when both equilibrium simultaneously established in a vessel `{:(X(s),hArr,A(g),+,2B(g),,,),(,,x,,(2x+2y),,,,),(Y(s),hArr,C(g),+,2B(g),,,),(,,y,,(2y+2x),,,,), (,(K_(p_(1)))/(K_(p_(2))),=(x)/(y),rArr,x=2y,,,),(K_(p_(1)),=x(2x+2y)^(2),rArr,,x=0.1atm,,:.,y=0.05atm,):}` Total pressure of gases `=P_(A)+P_(B)+P_(C )=3(x+y)=0.45atm.`
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Two solids X and Y dissociate into gaseous products at a certain temperature as follows: i. X(s) hArr A(g)+C(g) and ii. Y(s) hArr B(g)+C(g) At a given temperature, pressure over excess solid 'X' is 40 mm of Hg and total pressure over solid 'Y(s)' is 60 mm of Hg. Now, answer the following questions: The ratio of moles of A and B in the vapour state over a mixture of solids X and Y, is:
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Two solid X and Y dissociate into gaseous products at a certain temperature as followas: X(s)hArrA(g)+C(g) , and Y(s)hArrB(g)+C(g) At a given temperature, the pressure over excess solid X is 40 mm and total pressure over solid Y is 80 mm . Calculate a. The value of K_(p) for two reactions. b. The ratio of moles of A and B in the vapour state over a mixture of X and Y . c. The total pressure of gases over a mixture of X and Y .
Two solids dissociates as follows A(s) rarr B(g) + C(g), K_(P_(1)) = x atm^(2) D(s) rarr C(g) + E(g), K_(P_(2)) = y atm^(2) The total pressure when both the solids dissociate simultaneously is :
Solid A and B are taken in a closed container at a certain temperature. These two solids decompose and following equilibria are established simultaneously A(s)hArr X(g) + Y(g) K_(P_(1)) = 250 atm^(2) B(s)hArrY(g) + Z(g) K_(P_(2)) = ? If the total pressure developed over the solid mixture is 50 atm. Then the value of K_(P) for the 2^(nd) reaction.
