Home
Class 11
CHEMISTRY
A solution containing 0.2 mole of dichol...

A solution containing `0.2` mole of dicholoracetice acid `(K_(a)=5xx10^(-2))` and0.1 mole sodium dicholoroacetate in one litre solution has `[H^(+)]` :

A

`0.05M`

B

`0.025M`

C

`0.10M`

D

`0.005M`

Text Solution

Verified by Experts

The correct Answer is:
1

Since `CHCl_(2)COOH` is relatively strongs acid havings more `K_(a)`
`{:(CHCl_(2)COONa,rarr,CHCl_(2)COO^(-),+,Na^(+)),(,,0.1,,0.1),(CHCl_(2)COOH,hArr,CHCl_(2)COO^(-),+,H^(+)),(0.2,,0,,0),((0.2-x),,(x+0.1),,x):}`
`:. " "K_(a)=([CHCl_(2)COO^(-)][H^(+)])/([CHCl_(2)COOH])`
or `" "5xx10^(-2)=([0.1+x][x])/([0.2-x])`
`:." "x=0.05`
Promotional Banner

Topper's Solved these Questions

  • HYDROGEN AND ITS COMPOUNDS

    RESONANCE|Exercise INORGANIC CHEMISTRY(Hydrogen & its compunds Y environment chemistry)|33 Videos
  • MOLE CONCEPT

    RESONANCE|Exercise PHYSICAL CHEMISTRY(STOICHIOMETRY)|51 Videos

Similar Questions

Explore conceptually related problems

The pH of basic buffer mixtures is given by : pH=pK_(a)+log((["Base"])/(["Salt"])) , whereas pH of acidic buffer mixtures is given by: pH= pK_(a)+log((["Salt"])/(["Acid"])) . Addition of little acid or base although shows no appreciable change for all practical purpose, but since the ratio (["Base"])/(["Salt"]) or (["Salt"])/(["Acid"]) change, a slight decrease or increase in pH results in. A solution containing 0.2 mole of dichloroacetic acid (K_(a)=5xx10^(-2)) and 0.1 mole sodium dichloroacetate in one litre solution has [H^(+)] :

The Ph of basic buffer mixtures is given by : Ph=Pk_(a)+ log (["Base"])/(["Salt"]) whereas Ph of acidic buffer mixtures is given by : Ph = pK_(a)+"log"(["Salt"])/(["Acid"]) . Addition of little acid or base although shows no appreciable change in Ph for all practical purposes, but sicne the ratio (["Base"])/(["Salt"]) or (["Salt"])/(["Acid"]) changes, a slight decrease or increase in pH results. A solution containing 0.2 mole of dichloroacetic acid (K_(a)=5xx10^(-2)) and 0.1 mole sodium dichloracetate in one litre solution has [H^(+)] :

A one litre solution contains 0.08 mole of acetic acid (K_(a)=1.75xx10^(-5)) . To the solution, 0.02 mole of NaOH is added. Then the P^(H) of resulting solution is [log 1.75=0.273]

A one litre contains 0.08 moleof acetic acid (K_(a) = 1.75 xx 10^(-5)) . To this solution of resulting solution is [log 1.75 = 0.243]

4g of NaOH was dissolved in one litre of a solution containing one mole of acetic acid and one mole of sodium acetete. Find the pH of the resulting solution ( K_(a) of acetic acid is 1.8xx10^(-3) )

What amount of solution propanoate should be added to one litre of an aqueous solution containing 0.02 mole of propanoic acid ( K_(a)=1.0xx10^(-5) at 25^(@)C ) to obtain a buffer solution of pH 6

Calculate the hydrogen ion concentration ( "in mol"//dm^3 ) in a solution containing 0.04 mole of acetic acid and 0.05 mole of sodium acetate in 500 mL of solution.Dissociation constant for acetic acid is 1.75xx10^(-6) Report your answer after multiplying by 2xx10^(6)

The pH of buffer solution containing 4 xx 10^(-3) and 0.4 mole of acetic acid (pK_(a) = 4.76) and sodium acetate respectively will be

RESONANCE-IONIC EQUILIBRIUM-PHYSICAL CHEMITRY (Ionic Equilibrium)
  1. Calculate the pH of resulting solution obtained by mixing 50 mL of 0...

    Text Solution

    |

  2. 50ml N//10 NaOH solution is mixed with 50 ml N//20 HCl solution. The ...

    Text Solution

    |

  3. To prepare a buffer of pH 8.26, amount of (NH(4))(2)SO(4) to be added ...

    Text Solution

    |

  4. A solution containing 0.2 mole of dicholoracetice acid (K(a)=5xx10^(-2...

    Text Solution

    |

  5. The volume of 0.2 M NaOH needed to prepare a buffer of pH 4.74 with 50...

    Text Solution

    |

  6. The ratio of pH of solution (1) containing 1 mole of CH(3)COONa and 1 ...

    Text Solution

    |

  7. Equal volumes of two HCl solutions of pH=3 and pH=5 were mixed. What i...

    Text Solution

    |

  8. pOH of 0.002 MHNO(3) is :

    Text Solution

    |

  9. To a 10mL of 10^(-3) N H(2)SO(4) solution water has been to make the t...

    Text Solution

    |

  10. A weak base MOH of 0.1N concentration shows a pH value of 9 . What is ...

    Text Solution

    |

  11. Calculate the [OH^(-)] in 0.01M aqueous solution of NaOCN(K(b) for OCN...

    Text Solution

    |

  12. What will be the pH and % alpha ( degree of hydrolysis ) respectively ...

    Text Solution

    |

  13. 50mL of a solution containing 10^(-3) mole of Ag^(+) is mixed with 5...

    Text Solution

    |

  14. The solubility product of AgCl is 10^(-10)M^(2). The minimum volume ( ...

    Text Solution

    |

  15. What is the molar solubility of Ag(2)CO(3)(K(sp)=4xx10^(-13)) in 0.1M ...

    Text Solution

    |

  16. A solution saturated in lime water has a pH fo 12.4. Then the Ksp for ...

    Text Solution

    |

  17. Find the DeltapH( initial pH - final pH) when 100 ml 0.01M HCl is adde...

    Text Solution

    |

  18. If the solubility of Ag(2)SO(4) in 10^(-2)M Na(2)SO(4) solution be 2xx...

    Text Solution

    |

  19. 10mL of a strong acid solution of pH=2.000 are mixed with 990 mL of a...

    Text Solution

    |

  20. At infinite dilution, the percentage dissociation of both weak acid an...

    Text Solution

    |