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In the process of extraction of gold. ...

In the process of extraction of gold.
Roasted gold ore `+CN^(-)+H_(2)O overset(O_(2))rarr [X]+OH^(-)`
`[X]+Znrarr [Y]+Au`
Identify the complexes `[X] ` and `[Y]`.

A

`X=[Au(CN)_(2)]^(-),Y=[Zn(CN)_(4)]^(2-)`

B

`X=[Au(CN)_(4)]^(3-),Y=[Zn(CN)_(4)]^(2-)`

C

`X=[Au(CN)_(2)]^(-),Y=[Zn(CN)_(5)]^(4-)`

D

`X=[Au(CN)_(4)]^(-),Y=[Zn(CN)_(4)]^(2-)`

Text Solution

Verified by Experts

The correct Answer is:
1

`Au+2CN^(-)+H_(2)O+.^(1)//_(2)O_(2)rarr[Au(CN)_(2)]^(-)(X)+2OH^(-),2[Au(CN)_(2)]^(-)+Zn=[Zn(CN)_(4)]^(2-)(Y)+2Au`
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