Home
Class 12
CHEMISTRY
[Cr(H2 O)6]Cl3 (at no. of Cr = 24) has a...

`[Cr(H_2 O)_6]Cl_3` (at no. of Cr = 24) has a magnetic moment of `3.83 B.M`. The correct distribution of `3d` electrons the chromium of the complex.

A

`3d_(xy)^(1),3d_(yz)^(1),3d_(x x)^(1)`

B

`3d_(xy)^(1),3d_(yx)^(1),3d_(z^(2))^(1)`

C

`3d_((x^(2)-y^(2)))^(1),3d_(z^(2))^(1),3d_(zx)^(1)`

D

`3d_(xy)^(1),3d_((x^(2)-y^(2)))^(1),3d_(yz)^(1)`

Text Solution

Verified by Experts

The correct Answer is:
1

`[Cr(H_(2)O)_(6)]Cl_(3)` have `Cr^(3+)` having`d^(3)` configuration since it is octahedral complex . Thus electrons are filled in `t_(2g)` orbitals `(d_(xy)^(1),d_(yz)^(1),d_(zx)^(1))` . Thus it have configuration as `t_(2g)^(3)eg^(@)`
Promotional Banner

Topper's Solved these Questions

  • COORDINATION COMPOUNDS

    RESONANCE|Exercise Additional Problem for Self Practice (APSP) Part-IV Practice Test -2 (Section-5) (Matching Lift type )|1 Videos
  • D BLOCK ELEMENTS

    RESONANCE|Exercise EXERCISE-3 PART-III|37 Videos

Similar Questions

Explore conceptually related problems

A complex compound of chromium has magnetic moment 3.83 BM. Calculate the number of unpaired electrons.

Complex X of composition Cr(H_(2)O)_(6)Cl_(n) has a spin only mangnetic moment of 3.83 BM. It reacts with AgNO_(3) and shows geometrical isomerism. The IUPAC nomenclature of X is

A Complex P of compositon Cr(H_2O)_(6)Br_(n) has a spin only magnetic moment of 3.83 BM . It reacts with AgNO_3 and shows geometrical isomerism. The IUPAC nomenclature of P is

The magnetic moment of the complex [Ti(H_(2)O)_(6)]^(3+) is

One unpaired electron in an atom distributes a magnetic moment of 1.1 B.M. Calculate the magnetic moment of chromium (Cr=24)

For a tetrahedral complex [MCl_(4)]^(2-) , the spin-only magnetic moment is 3.83 B.M. The element M is -

RESONANCE-D & F BLOCK ELEMENTS-INORGANIC CHEMISTRY(d & f- Block Elments)
  1. In which of the following reaction "Philosopher's wool" is formed

    Text Solution

    |

  2. CrO3 dissolves in aqueous NaOH to give

    Text Solution

    |

  3. Mercury on heating with aqua regia gives

    Text Solution

    |

  4. The formula of azurite is :

    Text Solution

    |

  5. Oxide of metal cation which is not amphoteric ?

    Text Solution

    |

  6. The ratio of mass of a diamagnetic substance in a magnetic field to it...

    Text Solution

    |

  7. CrO(4)^(2-) (yellow) changes to Cr(2)O(7)^(2-)(orange ) in pH=y . Henc...

    Text Solution

    |

  8. An excess of Na(2)S(2)OO(3) react with aqueous CuSO(4) to give

    Text Solution

    |

  9. [Cr(H2 O)6]Cl3 (at no. of Cr = 24) has a magnetic moment of 3.83 B.M. ...

    Text Solution

    |

  10. Potassium manganate (K2MnO4) is formed when

    Text Solution

    |

  11. Uub is the symbol for the element with atomic number-

    Text Solution

    |

  12. Which of the following species has O-O bond?

    Text Solution

    |

  13. FeCr(2)O(4)( chromite ) is converted to Cr by following steps : Chro...

    Text Solution

    |

  14. When the same amount of zinc is treated separately with excess of sulp...

    Text Solution

    |

  15. Both [Ni(CO)4] and [Ni (CN)4]^(2-) are diamagnetic The hybridisation...

    Text Solution

    |

  16. Spin - only magnetic moment of [Co(NH(3))(3)(H(2)O)(3)]Cl(3)( in Bohr ...

    Text Solution

    |

  17. CO forms a volatile carbonyl complex with which of the following metal...

    Text Solution

    |

  18. Match List I with List II and select the correct answer using the code...

    Text Solution

    |

  19. Match List I with List II and select the correct answer using the code...

    Text Solution

    |

  20. The E(M^(3+)//M^(2+)^@ values for Cr, Mn, Fe and Co are 0.41, + 1....

    Text Solution

    |